三维交错多孔氧化铜纳米片的制备及其对葡萄糖的无酶检测.pdfVIP

Material Sciences 材料科学, 2017, 7(3), 309-317 Published Online May 2017 in Hans. /journal/ms /10.12677/ms.2017.73042 Preparation of Three-Dimensional Porous Copper Oxide Nanoflakes and Its Non-Enzymatic Detection of Glucose Changxu Shao, Shougang Chen* Department of Materials Science and Engineering, Ocean University of China, Qingdao Shandong rd rd th Received: May 3 , 2017; accepted: May 23 , 2017; published: May 26 , 2017 Abstract In this paper, three-dimensional porous copper oxide nanoflakes were successfully synthesized on the copper substrate without the use of organic reagents and stabilizers by the combination of liq- uid-solid reaction and high-temperature annealing. The three-dimensional porous structure of copper oxide has a large specific surface area, and the mesopores and micropores on the nano- sheets are conducive to the transmission of electron. Using good biocompatibility, conductivity and film of chitosan are used to prepare chitosan copper oxide organic-inorganic composite elec- trode for nonenzymatic glucose electrochemical sensor. This electrode has the advantages of sim- ple preparation, fast response and low detection line and the sensor is almost insensitive to com- mon interference, such as dopamine, uric acid and ascorbic acid. Keywords Porous Copper Oxide Nanoflakes, Non-Enzymatic Sensor, Glucose 三维交错多孔氧化铜纳米片的制备及其对葡萄 糖的无酶检测 邵长旭，陈守刚* 中国海洋大学材料科学与工程研究院，山东 青岛 收稿日期：2017年5月3 日；录用日期：2017年5月23 日；发布日期：2017年5月26 日 *通讯作者。 文章引用: 邵长旭, 陈守刚. 三维交错多孔氧化铜纳米片的制备及其对葡萄糖的无酶检测[J]. 材料科学, 2017, 7(3): 309-317. /10.12677/ms.2017.73042 邵长旭，陈守刚 摘 要 本文采用液固反应与高温退火相结合的方法，在不使用有机试剂及稳定剂的条件下在铜基体上成功的合