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合成Ru(bpy)2最早的文献
3334 Inorganic Chemistry, Vol. 17, No. 12, 1978 Sullivan, Salmon, and Meyer
of Wen, and W,,, are quite separate and independent, and there
1.401 r/l is no reason why a small W,,, should not be accompanied by
a large We,,or a large W,,, accompanied by a small Wenv.ll
If We,is zero or near zero, then the ion pair behavior should
be described by W,,, and thus be independent of temperature.
This is clearly not the case in the present study. Gurney” has
shown that the term We,, can be considered to be almost
entirely electrostatic in nature and may be represented by We,
which is proportional to the dielectric constant, t, of the solvent.
If we now consider the case of pure electrostatic forces, that
I is W,,, = 0, the values of log K would lie on a curve passing
280 290 300 310 320 340 through a minimum a t 219 K, the characteristic constant for
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