具有高二阶极化率噻唑类生色分子的合成与表征Synthesisand.PDFVIP

2006 年第64 卷 化 学 学 报 Vol. 64, 2006 第4 期, 343～347 ACTA CHIMICA SINICA No. 4, 343～347 ·研究论文· 具有高二阶极化率噻唑类生色分子的合成与表征 钟爱民 周钰明* 邱凤仙 (东南大学化学化工系 南京 210096) 摘要 设计、合成了含羟乙基活性基团的噻唑类非线性生色分子, 用IR, EA, 1H MNR, UV-Vis 和DSC-TG 等对其结构 和性能进行了表征, 用超瑞利散射技术测定了其二阶极化率. 结果表明: 两种噻唑类生色分子具有较高的β 值, 在波长 1064 nm 处, β 分别为5.60 ×10－28 和5.76 ×10－28 esu, 其最大吸收波长都未超过600 nm, 截止波长均小于710 nm, 生色 分子的热分解温度分别为 224 和216 ℃ , 具有较好的热稳定性, 可用于制备性能优异的非线性光学材料. 关键词 非线性; 噻唑; 生色分子; 超瑞利散射 Synthesis and Characterization of Thiazole Chromophores with High Second-order Polarizability ZHONG, Ai-Min ZHOU, Yu-Ming* QIU, Feng-Xian (Department of Chemistry and Chemical Engineering of Southeast University, Nanjing 210096) Abstract Two nonlinear optical thiazole chromophores with active hydroxyethyl group were designed and synthesized. The structures and properties of the organic molecules were characterized by IR, elemental 1 analysis, H MNR, UV-vis and DSC-TG. The second order nonlinear optical properties of both were deter- mined by hyper Rayleigh scattering method. The results show that the compounds have high β values of －28 －28 5.60 ×10 and 5.76 ×10 esu at 1064 nm wavelength, respectively. The maximum absorption wave- lengths of the compounds were less then 600 nm, and their critical wavelengths below 710 nm. These com- pounds were thermally stable with the decomposition temperature of 224 and 216 ℃, respecti