贵金属@TiO2.pdf

Nano Res (2010) 3: 244–255 244 Nano Res (2010) 3: 244–255 DOI 10.1007/s12274-010-1027-z Research Article Large Scale Photochemical Synthesis of M@TiO Nanocomposites 2 (M = Ag, Pd, Au, Pt) and Their Optical Properties, CO Oxidation Performance, and Antibacterial Effect 1,† 2,† 3 1 1 3 1 Shao Feng Chen , Jian Ping Li , Kun Qian , Wei Ping Xu , Yang Lu , Wei Xin Huang and Shu Hong Yu () 1 Division of Nanomaterials Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, Department of Chemistry, University of Science and Technology of China, Hefei 230026, China 2 School of Pharmacy, Anhui University of Traditional Chinese Medicine, Hefei 230026, China 3 Division of Chemical Physics, Hefei National Laboratory for Physical Sciences at Microscale, Department of Chemistry, University of Science and Technology of China, Hefei 230026, China Received: 11 November 2009 / Revised: 12 January 2010 / Accepted: 28 January 2010 © The Author(s) 2010. This article is published with open access at S ABSTRACT Well-dispersed M@TiO (M = Ag, Pd, Au, Pt) nanocomposite particles with a diameter of 200–400 nm can be 2 synthesized on a large scale by a clean photochemical route which does not require any additives using spherical rutile nanoparticles as a support. The sizes of Pt, Au, and Pd nanoparticles formed on the surface of TiO2 particles are about 1 nm, 5 nm, and 5 nm, respectively, and the diameter of Ag nanoparticles is in the range 2–20 nm. Moreover, the noble metal nanoparticles have good dispersity on the particles of t