【精选】jp0515885Synthesis and Characterization of Organofunctionalized MCM-41 by the Original Stepped.pdfVIP

J. Phys. Chem. B 2005, 109, 2431924325 24319 Synthesis and Characterization of Organofunctionalized MCM-41 by the Original Stepped Templated SolGel Technology Cui Zhang, Wei Zhou, and Shuangxi Liu* Institute of New Catalytic Materials Science, College of Chemistry, Nankai Uni ersity, Tianjin 300071, People’s Republic of China Recei ed: March 29, 2005; In Final Form: October 26, 2005 Four types of organofunctionalized (by phenyl, 3-aminopropyl, 3-chloropropyl, and N-aminoethylaminopropyl, respectively) mesoporous silicates MCM-41 (hereafter R-MCM-41) have been successfully synthesized via the grafting method, the conventional templated solgel technology, and the original stepped templated sol gel technology. The prepared inorganicorganic hybrid materials were characterized in detail by powder X-ray diffraction (XRD), 29Si and 13C MAS NMR spectrometry, isothermal nitrogen adsorptiondesorption analysis, FT-IR spectrometry including in situ drift technique, and thermogravimetric analysis (TGA). Through a series of investigations and comparisons, the advantageous stepped templated solgel technology introduced in this paper is demonstrated to be a remarkable approach that gathers the superior properties of the current grafting method and the conventional hydrothermal co-condensation synthesis, yielding as a consequence both thermodynamically firm fixation and relatively large content of organic functional species on the MCM- 41 support. The novel synthetic strategy also evidently shortens the crystallization time for the organo-