磨矿试验及粒度分析对浮选的影响-有色金属科学与工程.DOCVIP

某高品位钼铋硫化矿选矿试验研究 李立园1,聂庆民1,钟建峰1,艾光华1,2* （1江西理工大学，江西 赣州，341000；2，江西 赣州，341000）内蒙古某钼铋多金属硫化矿，含钼0.65%，含铋1.12%，钼铋品位较高，有较大的工业回收价值。采用“混合浮选—钼铋分离”的选矿工艺回收该矿石中的有用矿物，乙硫氮和煤油作为捕收剂进行混合浮选，硫化钠和亚硫酸钠作为组合抑制剂，煤油为捕收剂进行钼铋分离，最终实验室小型闭路试验可以获得含钼47.31%，钼回收率89.52%的钼精矿和含铋42.64%，铋回收率86.04%的铋精矿，较好地实现了钼铋分离。 tudy on A High Grade Molybdenum-Bismuth Sulfide Ore LI Liyuan1 NIE Qingmin1 ZHONG Jianfeng1 Qiu Tingsheng1,2 (1. School of Resources and Environment Engineering, Jiangxi University of Science and Technology，Ganzhou 341000; 2.Jiangxi Key Laboratory of Mining Engineering, Ganzhou 341000) Abstract：A molybdenumbismuth polymetallic sulfide ore in Inner Mongolia, includes 0.65% of molybdenum and 1.12% of bismuth. Due to the grade of molybdenum and bismuth are high, the molybdenum-bismuth polymetallic sulfide ore has a large industrial recovery value. The process of “Mixed flotation-separation of molybdenum-bismuth” was carried out to recover the useful minerals. The diethyldithiocarbamate and kerosene were used as collector in mixed flotation. The sodium sulfide and sodium sulfite were used as composite depressant and kerosene as collector for molybdenum-bismuth separation. The small closed-circuit test eventually had a molybdenum concentrate with 47.31% of molybdenum、89.52% of molybdenum recovery and a bismuth concntrate with 42.64% of bismuth、86.04% of bismuth recovery. The separation of molybdenum-bismuth was realized. Key words：molybdenum bismuth sulfide ore；ixed-flotation； separation of molybdenum-bismuth；composite collectorcomposite depressant 钼是钢铁行业不可或缺的金属材料，由于其密度小、强度高等特性而广泛应用于合金制造、电子器件制造及化工领域等。铋化学性质稳定，熔点较低，广泛应用于易熔合金制造、化工、半导体等领域。我国钼铋矿储量丰富，且钼铋普遍共生，由于钼铋硫化矿的可浮性相似，因此钼铋硫化矿的分离仍是一个难题[1]。内蒙古某钼铋多金属硫化矿，含钼0.65%，含铋1.12%，矿石中矿物组成复杂，有用矿物嵌布粒度较细，钼铋共生关系紧密，且铋品位高达1.12%，导致钼铋分离困难。为综合回收矿石中的有用矿物，减少钼铋互含，提高钼铋精矿回收率，本文以该矿为研究对象，进行了选矿试验研究。试验采用“混合浮选—钼铋分离”的浮选工艺，以硫化钠与亚硫酸钠作为组合抑制剂进行钼铋分离。试验结果表明该工艺可以较好地回收钼、铋矿物，实现了钼铋浮选分离。 1 试验 1.1试样性质 原矿钼铋含量较高，含钼0.65%，含铋1.12%，表1 原矿化学多元素分析结果 /%Tab. 1 Analysis results of chemical composition