荷电膜的膜电位研究3.PDF

第 18 卷 第 12 期 化　学　进　展 Vol. 18 No. 12 2006 年 12 月 PROGRESS IN CHEMISTRY 　Dec. , 2006 荷电膜的膜电位研究 张亚萍1 , 2 　徐铜文1 ( 1. 中国科学技术大学化学系 　合肥 230026 ; 2. 西南科技大学材料科学与工程学院 　绵阳 621010) 摘 　要 　膜电位是表征荷电膜传递现象的重要参数之一。本文简要介绍了膜电位理论基础 ,包括 T. M. S. 理论和不可逆热力学理论。分别阐述了关于离子交换膜、双极膜、两性膜以及复合膜的膜电位的最新进 展 ,并提出今后的发展方向。 关键词 　膜电位 　离子交换膜 　双极膜 　两性膜 　复合膜 ( ) 中图分类号: O4844 ; TQ0288 　文献标识码 : A 　文章编号 : 1005281X 2006 The Membrane Potential Across Charged Membranes 1 ,2 1 Zhang Yaping 　Xu Tongwen ( 1. Department of Chemistry , University of Science and Technology of China , Hefei 230026 , China ; 2. Material Science and Engineering College , Southwest University of Science and Technology , Mianyang 621010 , China) Abstract 　The membrane potential is one of the most important parameters for characterizing transport phenomena across a charged membrane. The fundamental theories of membrane potential including T. M. S. theory and irreversible thermodynamic theory are briefly introduced. Further , the developments of membrane potential across such membranes as ion exchange membrane , bipolar membrane , amphoteric membrane and composite membrane are reviewed respectively. Finally , the prospects of the membrane potential in charged membranes are presented. Key words 　membrane potential ; ion exchange membrane ; bipolar membrane ; amphoteric membrane ; composite membrane 具有无污染和产率高的优点[6 ] ;荷电纳滤膜可以用 1 　引言