顺丁橡胶生物质填料复合材料压缩永久变形的研究.docx

顺丁橡胶/生物质填料复合材料压缩永久变形的研究Study On the Compression Set of BR Composites Filled With a Biomass Filler彭丽敏 1，罗琼林 1，徐建双 2，熊晨 2，苏胜培 1?(1. 湖南师范大学 化学化工学院 资源精细化与先进材料重点实验室，湖南 长沙 410081；2. 深圳博富隆生物质 新材料工程研究院，广东 深圳 518118)PENG Li-min1, LUO Qiong-Lin1,XU Jian-shuang2, XIONG Chen2,SU Sheng-pei1*(1. College of Chemistry and Chemical Engineering, Key Lab of Sustainable Resources Processing and Advanced Materials, Hunan Normal University, Changsha 410081, China; 2. Prosperous Biomass New Material Engineering Institute, Shenzhen 518118, China)摘要：造纸工业以往治理废水的方法主要是碱回收法，将废水即黑液进行浓缩，再燃烧，后回收 碱，这种做法造成的污染严重。黑液中的木质素可以修饰蒙脱土，可为橡胶工业提供一种性能优异 的生物质纳米填料，减少了黑液对环境造成的污染。本报告主要介绍了黑液-蒙脱土的制备及其运用 于顺丁橡胶中压缩永久变形的研究。通过机械混炼制备了顺丁橡胶/黑液-蒙脱土（NBR/BL-MMT） 复合材料，分别从填料类型及用量、交联键、界面作用三个方面来讨论其压缩永久变形的变化规律。 研究表明：BL-MMT 填充补强 BR，其压缩永久变形性能优于相同份数炭黑补强的 BR；交联键类型 很大程度上会影响 BR/BL-MMT 复合材料压缩永久变形性能，过氧化物硫化体系硫化形成的碳碳键 键能较高，对应的硫化胶压缩永久变形较小；橡胶基体与填料之间的界面作用对其压缩永久变形同 样有影响。关键词：黑液-蒙脱土；生物质填料；顺丁橡胶；压缩永久变形 中图分类号：文献标志码：文章编号：Abstract: Alkali recovery is mainly the method for the previous treatment of wastewater in paper industry. Wastewater, also called black liquor, was concentrated, and next was burned, then was recovered with base. Lignin in black liquor can be modified by montmorillonite, providing a kind of biomass nano-fillers with excellent performance for the rubber industry and reducing the environmental pollution caused by black liquor. This report has described the preparation of black liquor-montmorillonite and studied on the compression set of butadiene rubber/black liquor-montmorillonite composites (NBR/BL-MMT).The influence of the loading and types of filler, crosslinks, and additions on the compression set variation of NBR/BL-MMT composites was discussed respectively. The results showed that the compression set of vulcanizates filled with BL-MMT was better than that with equal carbon. The type of Crosslinks affected the compression performance of BR/BL-MMT composites in a degree, while carbon-carbon bond formed with peroxide curing system