[(CH3)3NC16H33]4W10O32H2O2[Bmim]PF6 离子液体乳液催化氧化脱硫性能的研究.pdfVIP

Advances in Environmental Protection 环境保护前沿, 2014, 4, 112-122 Published Online August 2014 in Hans. /journal/aep /10.12677/aep.2014.44016 Catalytic Oxidative Desulfurization Using [(CH ) NC H ] W O /H O /[Bmim]PF 3 3 16 33 4 10 32 2 2 6 System * Jianhua Ge , Liangmin Gao, Shaomin Liu, Youbiao Hu 1 School of Earth Science and Environmental Engineering, Anhui University of Science Technology, Huainan 2 Key Laboratory of Mine Geological Hazard and Control, Huainan * Email: gejianhua13@163.com th nd nd Received: May 25 , 2014; revised: Jun . 22 , 2014; accepted: Jul. 2 , 2014 Copyright © 2014 by authors and Hans Publishers Inc. This work is licensed under the Creative Commons Attribution International License (CC BY). /licenses/by/4.0/ Abstract Sulfur-containing compounds in transportation fuels are converted by combustion to SOx, which is a major source of air pollution and damages exhaust devices. For the environmental protection purpose, in the paper, hydrophobic ionic liquid 1-butyl-3-methylimidazolium hexafluorophos- phate ([Bmim]PF6) and surfactant-type decatungstate were synthesized and characterized by means of FT-IR, UV-Vis and TG-DSC. The amphiphilic decatungstate was assembled in hydrophobic ionic liquid emulsions system with 30 wt% H2O2 as oxidant, which has been found suitable for the deep removal of DBT in fuels. In this catalytic oxidation desulfurization system, the role of the ma