中空纤维膜液相微萃取–气相色谱法测定水中有机氯农药的研究.pdfVIP

Water Pollution and Treatment 水污染及处理, 2014, 2, 19-27 Published Online July 2014 in Hans. /journal/wpt /10.12677/wpt.2014.23004 Study on the Determination of Organo-Chlorine Pesticides in Water by Method of Hollow Fiber Membrane Liquid Microextraction-Gas Phase Chromatography 1 1 1 2 2 2* Jie Xu , Xiufeng Li , Xianfeng Chu , Chiyuan Ma , Xiaoqin Wu , Yongquan Dong 1 Jiangxi Province Environmental Monitoring Centre, Nanchang 2 Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, College of Environmental Chemical Engineering, Nanchang Hangkong University, Nanchang * Email: dongyongquan@ th th th Received: Jun. 15 , 2014; revised: Jul. 5 , 2014; accepted: Jul. 10 , 2014 Copyright © 2014 by authors and Hans Publishers Inc. This work is licensed under the Creative Commons Attribution International License (CC BY). /licenses/by/4.0/ Abstract The determination method for organo-chlorine pesticide in water using hollow fiber membrane liquid microextraction coupling with gas phase chromatography was developed. The effects of ex- tracting system, extraction time, pH value, mixing speed and extraction temperature on recovery of organo-chlorine pesticide in water were investigated and the optimum extraction conditions were gained and listed as follows: using n-hexane/toluene as organic extractant, extraction time of 20 min, extraction temperature of 40℃, mixing speed of 500 rpm, neutral solution. Under the op- timum conditions, the recovery rates of α-666, β-666, γ-666, δ-666, P,p’-DDE, P,p’-DDD, o,