硅油改性醋丙乳液在涂料染色中的应用 application of new silicone modified vinyl acetate acrylate to pigment dyeing.pdfVIP

硅油改性醋诹乳液在涂料染色中的应用 印染(2013No．1) 硅油改性醋丙乳液在涂料染色中的应用 张文博，赵振河，张鹏 (西安工程大学纺织与材料学院，陕西西安710048) 摘要：采用醋酸乙烯酯和丙烯酸酯类单体，以及乙烯基硅油和少量的可聚合乳化剂，以半连续种子乳液聚 合法制备硅油改性无皂醋丙乳液，并用红外光谱及激光粒度仪对产物进行表征。将硅油改性的醋丙乳液作 为黏合剂，应用于棉织物涂料染色，优化的工艺为：硅油改性醋丙乳液5％、涂料0．5％、外加交联剂0．5％； 80℃预烘3min，150℃焙烘3min。结果表明，以硅油改性无皂醋丙乳液为黏合剂的涂料染色织物的干湿摩 擦牢度、耐皂洗牢度与传统黏合剂的相当，且手感较柔软。 关键词：有机硅改性；醋丙乳液；无皂；黏合剂；涂料染色；棉织物 中图分类号：TSl93．64文献标识码：A 文章编号：1000—4017(2013)01—0009—04 ofnewsiliconemodifiedacetate to Application vinyl acrylatepigmentdyeing ZHANG Wen-bo，ZHAOZhen·he，ZHANGPeng andMaterials ofTextiles Science。Xi{znUniversity 710048，China) (College ofEngineering，施缸n siliconemodified emulsionis and Abstract：A soap—freevinylacetate—acrylatesynthesizedusingpre··emulsification with oilandasmallamountofthe e- OUS method silicone adding vinylacetate(VAC)，acrylicmonomers。vinyl polymerizable structureischaracterizedFT-lRandlaser size modified emulsion mulsifier．its by particleanalyzer．Siliconevinylacetate-acrylate the issiliconemodified emulsion is tocotton as adhesives．The applied pigmentdyeing optimalprocess vinylacetate·acrylate resultsshowthatthecolor linker at80℃for3 at150℃for3min．The 0．5％，cross0．5％，drying min，curing 5％，pigment fastnessesto and ofthe aresimilartothatoftraditional thehandfeel wet／dryrubbingsoapingpigmentdyeings adhesives，and