冶金废渣激发剂的制备.docVIP

摘 要 冶金废渣是指各种金属在冶炼过程中或冶炼后排出的所有废物。因为它是在高温下形成的，具有不稳定的结构特征，所以具有潜在的活性，可以通过制备它们的激发剂以激发它们的活性，生产出许多各种新型建筑材料。本实验以铁矿渣，粉煤灰，煤矸石为原料，选用氢氧化钙，硫酸钙，氢氧化钠，碳酸钠，硅酸钠等药品制备其激发剂。 实验中考察了不同配料比，水灰比，反应时间，反应温度，介质的pH，养护时间，养护温度等反应因素对最终产品质量的影响。经过反复实验优化选择制备出对原材料激发效果最好的激发剂：铁矿渣选用氢氧化钠作为激发剂；粉煤灰选用氢氧化钙和硫酸钙作为激发剂；煤矸石选用氢氧化钙和硫酸钙作为激发剂。 本工艺通过化学反应研制出的激发剂效果良好，原料廉价，生产设备简单。对激发剂激发废渣制作出来的试块进行性能测试，结果显示，具有较高的抗压强度，可以用于许多的建筑材料。 关键词：冶金废渣; 激发剂; 活性; 抗压强度 Abstract Metallurgical slag refers to all kinds of metal smelting in the process of smelting or after the smelting discharging all the crap. It has the potential activity because it is formed under the high temperature and has the structure of instability. We can prepare their activator to stimulate their activity and produce many new types of building materials. Iron slag, fly ash, gangue was selected as the stuff and calcium hydroxide, calcium sulfate, sodium hydroxide, sodium carbonate, sodium silicate, any other drugs were selected as the activator in the experiment. We examined the effects of different material ratio, water-cement ratio, reaction time, reaction temperature, medium pH value, conservation time as well as conservation temperature on the final product quality. After repeated experiments, we optimize to choose the best activator to the stuff. Iron slag selected sodium hydroxide as an activator. Fly ash selected calcium hydroxide and calcium sulfate as an activator. Gangue selected calcium hydroxide and calcium sulfate as an activator. This process through chemical reactions developed the good effect activator. Stuff is cheap, and production equipment is simple. We did a performance test to the test block where the metallurgical slag was stimulated by activator .The results showed that had high compressive strength. It could be used for many construction materials. Key words: metallurgical slag; activator; activity; compressive strength 目 录 第1章 绪 论 1 1.1引言 1 1.2 冶金废渣的来源及其特点 1 1.2.1 冶金废渣的来源 1 1.3 废渣活性的来源及其激发机理 2 1.3.1 矿渣活性的来源及其激发机理 2 1.3.2 粉煤灰活性的来源及其激发机理 2