脱脂工艺对热镀锌钢板表面特性的影响.pdfVIP

脱脂工艺对热镀锌钢板表面特性的影响 ·1 · 脱脂工艺对热镀锌钢板表面特性的影响 张剑萍 杨家云 （宝山钢铁股份有限公司研究院，上海 201900 ） 摘 要 分别采用水、有机溶剂和碱性脱脂剂水溶液对热镀锌涂油钢板进行脱脂清洗处理，并通过三维显微镜、辉 光光谱仪和电化学工作站研究了不同脱脂工艺对热镀锌钢板表面形貌、元素成分及表面反应活性的影响。结果显示 不同脱脂工艺对热镀锌板表面形貌无影响，且三种脱脂工艺均能够有效清洁热镀锌板表面油污。水和有机溶剂脱脂 工艺能够保留热镀锌板表面氧化层，但碱脱脂工艺会破坏其表面氧化层，因此会影响热镀锌钢板表面的反应活性。 电化学数据表明采用有机溶剂脱脂工艺可以保持热镀锌板表面的氧化膜状态不发生变化，因此其表面反应活性相对 较低；采用水和碱脱脂工艺会改变热镀锌板表面氧化膜结构，会提高热镀锌表面反应活性。 关键词 脱脂工艺，热镀锌钢板，表面元素，电化学，表面反应活性 Effect of Degreasing Process on Surface Property of Galvanized Steel Sheet Zhang Jianping, Yang Jiayun (Research Institute, Baoshan Iron Steel Co., Ltd., Shanghai 201900, China) Abstract The galvanized steel sheets with antirust oil were degreased by neutral water, organic solvent and alkaline aqueous solution, respectively, and the effects of degreasing process on surface morphology, surface elements and surface reaction activity of the galvanized steel sheets were investigated by 3D microscope and electrochemical workstation. The results showed that three kinds of degreasing methods could effectively clean the antirust oil on the surface of galvanized steel sheets and had a little relationship with surface morphology of galvanized steel sheets. The electrochemical results proved that the solvent-degreasing process could keep the oxide film on the surface of galvanized steel sheet, which led to low surface reaction activity of the sheet. The neutral water-degreasing and alkaline-degreasing process would ruin the oxide film of galvanized steel sheet, and this would improve surface reaction activity of the sheet. Key words degreasing process, galvanized steel sheet, surface element composition