丙烯酰胺与甲基丙烯酰氧乙基三甲基氯化铵反相乳液聚合-化工学报.PDF

研究论文 DOI: 10.11949/j.issn.0438-1157 丙烯酰胺与甲基丙烯酰氧乙基三甲基氯化铵反相乳液聚合动力学 陈勇，单国荣1 （化学工程联合国家重点实验室，浙江大学化学工程与生物工程学院，浙江杭州 310027 ） 摘要：以丙烯酰胺（AM ）和甲基丙烯酰氧乙基三甲基氯化铵（DMC ）为单体，失水山梨糖醇脂肪酸酯（Span 80 ）和 失水山梨醇单油酸酯聚氧乙烯醚（Tween 80 ）为乳化剂，液体石蜡为油相，2,2’-偶氮二异丙基咪唑啉二盐酸盐（VA-044 ） 为引发剂，研究AM 与DMC 反相乳液聚合动力学，反相乳液聚合速率方程为Rp = k[M]2.12 [I]0.55[E]0.65 ，AM 与DMC 反 相乳液聚合表观活化能为80.65 kJ·mol-1 。通过反相乳液聚合速率随时间的变化关系得出其成核机理倾向于单体液滴成 核。用Fireman-Ross 法研究了共聚单体竞聚率，分别为rAM = 0.23 、rDMC = 1.93 ，AM 与DMC 在聚合物链上发生无规 共聚反应。单体量增大、引发剂量减少、乳化剂量增大、聚合温度降低均使共聚产物的特性黏数增大。 关键词：动力学；反相乳液；聚合；成核机理；特性黏数 中图分类号：TQ326.4 文献标志码：A 文章编号： Kinetics of acrylamide and 2-methylacryloylxyethyltrimethyl ammonium chloride in inverse emulsion polymerization CHEN Yong, SHAN Guorong （State Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, Zhejiang, China） Abstract ：Inverse emulsion polymerization kinetics of acrylamide (AM) and 2-methylacryloylxyethyl trimethylammonium chloride (DMC) has been investigated using the mixture of sorbitan monooleate (Span 80) and polyethylene glycol sorbitan monooleate (Tween 80) as the composite emulsifier, liquid paraffin as the oil phase and 2,2′-azobis[2-(2-imidazolin-2-yl) propane]-dihydrochloride as the initiator. The rate equation of AM and DMC inverse emulsion polymerization could be represented as Rp = k[M]2.12 [I]0.55 [E]0.65, and the apparent activation energy of AM and DMC inverse emulsion polymerization was 80.65 kJ·mol-1. Relationship of reaction rate change in AM and DMC inverse emulsion polymerization with time indicated that the nucleation mechanism tended to droplet nucleation. Monomer reactivity ratios of AM and DMC were determined as rAM = 0.23 ，rDMC =