河水化学之主要、微量元素及同位素分析与其相关应用.PDFVIP

河水化學之主要、微量元素及同位素分析與其相關應用 The analyses and applications of dissolved elements and isotopes in river water Ruo-Mei Wang (王若梅) Institute of Earth Sciences, Academia Sinica 樂盟應用研討 Introduction • Rock types • Slope and Uplift • Weathering intensity • Special climate events • Chemical weathering • Ground water Physical denudation • SGD • Water mass mixing Introduction Silicate mineral weathering reactions: CaSiO + 2CO + H O → 2HCO - + Ca2+ + SiO 3 2 2 3 2 Mg SiO + 4CO + 4H O -- 2Mg2+ + H SiO + 4HCO - 2 4 2 2 4 4 3 (Goudie and Viles, 2012) The relationship between weathering processes and the controlling factors (e.g. uplift, slope, temperature, rainfall) is essential to our understanding of long-term climate variability and global carbon cycles Analytical procedures Water sample Filtered with 0.20 μm filter Non-acidified sample Acidified with HNO3 to pH2 Chemical