硫化钠法合成PPS的溶剂和催化体系的考察-常州大学学报.PDF

( ) 绗 鍗 绗 鏈 甯稿窞澶у瀛︽姤 鑷劧绉戝鐗 锛掞紨 锛 Vol矶帮紥锛擭o矶帮紥 骞 鏈 ( ) 锛掞紣锛戯紥 锛 JournalofChanzhouUniversit NaturalScienceEdition Jun矶帮紥锛愶紤锛 g y 鏂囩珷缂栧彿: ( ) 锛掞紣锛欙紩锛嶏紣锛旓紤锛 锛掞紣锛戯紥 锛愶紥锛嶏紣锛愶紤锛楋紞锛愶紩 纭寲閽犳硶鍚堟垚PPS鐨勬憾鍓傚拰鍌寲浣撶郴鐨勮€冨療鈭 锛 锛 锛 锛 锛 , , , , 鍌ㄦ捣闇 鍗曠帀鍗 涓佹案绾 椴佸ⅷ寮 鏉庢槑鏃 ( , ; , ) 锛戫栋甯稿窞澶у 姹熻嫃鐪佺簿缁嗙煶娌瑰寲宸ラ噸鐐瑰疄楠屽 姹熻嫃 甯稿窞 锛掞紤锛擄紤锛栵紨 锛掜栋甯稿窞澶у 鏉愭枡绉戝涓庡伐绋嬪闄 姹熻嫃 甯稿窞 锛掞紤锛擄紤锛栵紨 : , ( ). 銆 鎽樿 浠ュ伐涓氱～鍖栭挔涓虹～婧 瀵逛簩姘嫰鍦ㄥ偓鍖栧墏鍜屽姪鍓傜殑浣滅敤涓嬬缉鑱氬悎鎴愯仛鑻～閱 PPS 鍒嗗埆鑰冨療 CH COONa PhCOO锛 锛 銆 銆 , , 銆 , 銆 ,, 銆 , 銆 Na LiPO CaL绛変负鍌寲鍓 N N锛嶄簩鐢插熀鑻兒 锛掞紩锛嶄簩姘鍩鸿嫰 锛戯紥锛旓紞涓夋隘鑻 瀵圭鍩鸿嫰閰氱瓑涓哄姪鍓 涓夋垔鑳 鐜 锛 锛 銆 ( )銆 ( )銆 , , , 涓佺牅 N锛嶇敳鍩哄挭鍞 NMI N锛嶇敳鍩哄悺鍜兎閰 NMP 鍚楀暋鍟夌瓑涓烘憾鍓 鍦 锛戯紬锛愶紞锛掞紤锛愨剝鍙嶅簲 锛揾 锛掞紥锛愶紞锛掞紨锛愨剝鍙嶅簲 锛攈 寰 . 銆 銆 銆 ; ( ). 鍒颁骇鍝丳PS 鐢ㄧ孩澶栧厜璋 鍏冪礌鍒嗘瀽 TGA DSC瀵规墍鍒跺 PPS杩涜琛ㄥ緛 鐢ㄧ壒鎬х矘搴︽硶娴嬪畾 PPS鐨勭浉瀵瑰垎瀛愯川閲 Mr : , ; 銆 , 缁撴灉琛ㄦ槑 浠 涓烘憾鍓 娣诲姞 鐨 鍙唬鏇挎憾鍓 鍚堟垚 浠ヨ嚜鍒剁殑缁滃悎鐗 涓哄偓鍖栧墏 浜岀敳鍩鸿嫰鑳 NMI 锛戯紩锛 NMP NMP PPS CaL N N锛 , , ( ) , . 浣滀负鍔╁墏 PPS鏀剁巼鍦 锛欙紥锛呬互涓 t 鐔旂偣 鍙揪 锛掞紭锛欌剝 M 涓 锛旓紭锛戯紮锛 m r : ; ; ; ; 鍏抽敭璇 鑱氳嫰纭啔 鍌寲鍓 婧跺墏 鍔╁墏 鍚堟垚 涓浘鍒嗙被鍙耳TQ锛擄紥锛掋€€銆€銆€銆€鏂囩尞鏍囪瘑鐮?A