蓖麻油聚氨酯丙烯酸酯复合乳液的研制-林产化学与工业.PDFVIP

25 1 Vo.l 25No. 1 2005 3 Chem istry and Industry of Forest Products M ar. 2005 * 瞿金清, 陈焕钦 (华南理工大学 化学工程研究所, 广东 广州 510640) : 采用甲基丙烯酸甲酯(MMA )与蓖麻 水性聚氨酯共聚反应制备蓖麻 聚氨酯丙烯 酸酯(CP A)复合乳液, 研究了蓖麻 添加量MMA 添加量和引发剂种类对合成 CP A复合乳 液及涂膜性能的影响,并应用傅立叶红外光谱( FT- IR)测定反应产物的结构研究发现随着 Q J Q 蓖麻 和MMA添加量增大, CP A 复合乳液胶粒平均粒径增大, 粘度减小, 涂膜光泽度下降, 机械性能和耐水性增强, 确定了合适的蓖麻 和MMA含量, 分别为体系总固体质量的 20% ~ 25%和 20% ~ 30% 采用偶氮二异 丁腈(A IBN )和过硫酸钾(KPS)复合引发剂可提高单体的转化率; 性能测试表明, 本研究 合成的 CP A 复合乳液具有优异的物理机械性能和耐水性 : 聚氨酯丙烯酸酯; 水性聚氨酯; 蓖麻 ; 复合乳液 : TQ630. 1; S565. 6 : A : 0253- 2417( 2005) 01- 0094- 05 ST DY ON SYNTHESIS OFHYBRID EM LSION OF CASTOR OIL WATER-BORNE POLY RETHANE-ACRYLATE Q Jin-qing, CHEN Huan-qin (Institu te of Chem ical E ng ineering, South Ch ina Un iv er sity of T echnology, Guangzhou 510640, Ch ina) A bstrac t: Hybrid emulsion of castor oilpolyurethane-acrylate(CP A) was prepared by co-polymerization of castor oil polyurethanew ith methylacrylate(MMA ). The effects of castor oil content, initiator type and MMA content on the properties ofCP A emulsion and its film were investigated. The structure ofCP A was characterized by FT-IR. Itwas found that mechanical properties and water resistance of CP A coating film and average particle size of CP A emulsion increased, and viscosity of CP A emulsions and glossiness ofCP A film decreasedw ith increasing ofMMA and castor oil contents, the optmi alMMA and castor oil contents were determ ined to be 20% - 33% and 20% - 25%, respectively. sing azo-bis-isobutyronitr