壳聚糖制碱性燃料电池阴离子交换膜的研究.pdfVIP

Sustainable Energy 可持续能源, 2017, 7(5), 89-96 Published Online October 2017 in Hans. /journal/se /10.12677/se.2017.75010 Research on Chitosan Anion Exchange Membrane for Alkaline Fuel Cell * Jun Hu, Jie Sun , Jigang Li, Tian Zhou, Jingjing Zhang Institute of NBC Defence, Beijing st th st Received: Aug. 31 , 2017; accepted: Sep. 14 , 2017; published: Sep. 21 , 2017 Abstract The anion exchange membrane (AEM) is the core components of alkaline polymer electrolyte membrane fuel cell (APEMFC), but it can’t be widely used due to the current problems of low hy- droxyl ion conductivity and poor stability. This paper attempted to use the biological material of chitosan (CS) to prepare AEM, and characterization and performance studies were carried out. In- troducing the inorganic materials of graphene oxide (GO) to the polymer matrix composite mem- branes to construct ion channels in order to improve the transmission rate, and using two types of material interaction to enhance membrane stability. It is found that the performance of the com- posite membrane is greatly improved compared with the chitosan membrane, and the ionic con- ductivity is more than 2 × 10−2 S∙cm−1, and the energy density under normal operation reaches −2 1.96 mW∙cm . Keywords Alkaline Fuel Cell, Anion Exchange Membrane, Chitosan, Graphene Oxide 壳聚糖制碱性燃料电池阴离子交换膜的研究 * 胡 军，孙 杰 ，李吉刚，周 添，张静静 防军防化学院，北京 收稿日期：2017年8月31 日；录用日期：2017年9月14 日；发布日期：2017年9月21 日 摘 要 阴离子交换膜(Anion Exchange Membrane, AEM)是碱性聚合物电解质膜燃料电池(Alkaline Polymer *通讯作者。 文章引用: 胡军, 孙杰, 李吉刚, 周添, 张静静.