完美骨架全硅β沸石性质研究-上海有机化学研究所.PDF

2002 年第 60 卷 化 学 学 报 Vol. 60 , 2002 第 3 期 , 451～456 ACTA CHIMICA SINICA No. 3 , 451 ～456 β 完美骨架全硅 沸石性质研究 Ⅱ. 有机吸附质的吸/ 脱附行为及其吸附热的测定 宋茂莹　　王喜庆　　钱　斌　　曾　宇　　龙英才 (复旦大学化学系 　上海 200433) 摘要 　运用热分析技术研究胺类、烷烃类、芳香烃类、醇类在具完美骨架的合成得到的全硅β沸石中的脱附行为 ,测 定亲和性指数 A T 值和负载量. 发现烷烃类、胺类、芳香族化合物都对全硅β沸石骨架表现出亲和性 ,而醇类由于羟 ( ) 基的存在表现出对骨架的憎性 ,结合吸附热等数据讨论了各类吸附质与骨架相互作用 主/ 客体相互作用 的性质. 关键词 　全硅β A 值 , 主客体相互作用 , 等量吸附热 , 相互作用能 沸石 , 完美骨架 , 热分析技术 , T Studies on Properties of Puresilica βZeolite Ⅱ. Adsorption/ Desorption Behavior and Isosteric Heat of Organic Adsorbates SONG, MaoYing 　　WANG, XiQing 　　QIAN , Bin 　　ZENG, Yu 　　LONG, YingCai ( Department of Chemistry , Fudan University , Shanghai 200433) Abstract 　The adsorption/ desorption behaviors of 17 organic compounds on synthetic pure silica BEA type zeolite were investigated by means of TG/ DTG/ DTA analysis. The organics used as the adsorbates were alkanes , aromatics , alcohols , and alkylamines. A T value , the affinity index determined by DTG was used to characterize the interaction between the organic adsorbates and the perfect [ Si —O ] framework of the zeolite. The hydrophobic framework of the zeolite shows stronger affinity to the organic molecules containing amino and alkyl groups than those with hydroxyl groups. The nature of the sorbate/ framework