丁二酸二正辛酯的催化合成及动力学研究.pdfVIP

丁二酸二正辛酯的催化合成及动力学研究 栾向海，孙晓波，刘焕，刘国际，蒋登高 （郑州大学化学工程学院，河南 郑州 450001 ） 摘要：以丁二酸和正辛醇为原料，环境友好型磷钨杂多酸为催化剂，甲苯为带水剂，合成了丁二酸二正辛 酯。由均匀设计法设计实验，考察了醇酸摩尔比，催化剂用量，带水剂用量和反应时间对酯化率的影响， 经单因素实验优化得到的最佳工艺条件为：醇酸摩尔比3.1 ：1，催化剂用量为酸质量的1.2%，带水剂用量 为酸质量的70% ，反应时间3 个小时，在较佳工艺条件下，酯化率达99.27% 。同时建立了该酯化合成的表 观动力学模型，得到的反应速率方程为： dCA 9 −85262RT −1 −1 。 r =− 2.250 =×10 e C C molgL gmin A B dt 关键词：丁二酸二正辛酯；杂多酸；均匀设计；酯化；动力学 中图分类号：O621.256.4 TQ225.242 文献标识码： Study on Catalytic Synthesis of Di-n-octyl Succinate and Its Raction Kinetics LUAN Xiang-hai, SUN Xiao-bo,LIU Huan,LIU Guo-ji,,JIANG Deng-gao (College of Chemical Engineering,ZhenZhou University,Zhengzhou 450002,Henan,China) Abstract:Di-n-octyl Succinate was prepared from succinic acid and n-octanol as reactant, by using environment-friendly phosphotungstic acid as catalyst and toluene as azeotropic agent.Molar ratio of n-Octanol to succinic acid,amount of catalyst,amount of azeotropic agent and reaction time were studied according to uniform design.The optimum reaction condition optimized by single-factor experiment were that the molar ratio of alcohol-acid 3.1:1,the amount of catalyst and azeotropic agent were 1.2% and 70% by mass of acid,reaction time 3 hours.under this condition,the yield of di-n-octyl adipate could reach 99.27%.The apparent knetics modle of esterification was established,and the equation of reaction rate was: dC −85262 =− A 2.250=×109 RT g −1gmin−1 r e C C mol L A B dt Keywords: di-n-octyl succinate; heteropoly acid;esterification; kinetics;uniform design