【精选】环糊精及其衍生物催化的有机反应.pdfVIP

DOI: 10.6023/cjoc201409001 综述与进展 有机化学 Chinese Journal of Organic Chemistry REVIEW 环糊精及其衍生物催化的有机反应 洪诗斌a,b 刘梦艳a,b 张 薇a,b 邓 维*,a,b (a 上海大学纳米科学与技术研究中心 上海 200444) (b 上海应用技术学院化工学院 上海 201418) 摘要 环糊精及其衍生物能将有机小分子等包合进疏水空腔, 改变有机小分子在水中的溶解性, 还能通过电荷作用影 响分子的电性环境. 环糊精还是天然的手性分子, 将环糊精及其衍生物用于催化有机反应不仅能使反应在温和的条件 下得到良好的收率, 还能运用于不对称合成. 本文就近年来环糊精催化的有机反应分五部分概述: 非修饰环糊精、金属 离子参与、无金属离子参与催化的有机反应以及它们在手性催化、光化学反应的运用. 关键词 环糊精; 超分子; 有机合成; 催化反应; 不对称合成 Organic Reactions Catalyzed by Cyclodextrin and Its Derivatives Hong, Shibina,b Liu, Mengyana,b Zhang, Weia,b Deng, Wei*,a,b a ( Research Center of Nano Science and Technology, Shanghai University, Shanghai 200444) b ( School of Chemical and Engineering, Shanghai Institute of Technology, Shanghai 201418) Abstract Cyclodextrin (CD) and its derivatives catalyzed organic reactions, including asymmetric reactions, show mild con- ditions with good yield. This review is an overview of recent advances of CD catalyzed reactions, which is organized in the order of the following reaction types: the modified cyclodextrin catalyzed organic reaction, cyclodextrin catalyzed organic reaction of metal ion present, cyclodextrin catalyzed organic reaction without metal ion, and cyclodextrin catalyzed organic reactions in application of asymmetric synthesis and photochemical reactions. Keywords cyclodextrin; supramolecule; organic synthesis; catalyst reactions; a