竹炭对甲醛的吸附性能研究-林产化学与工业.pdfVIP

25 1 Vo.l 25No. 1 2005 3 Chem istry and Industry of Forest Products M ar. 2005 * * 杨 磊, 陈清松 , 赖寿莲, 李晓燕, 叶桂足 (福建师范大学 化学与材料学院, 福建 福州 350007) : 采用分光光度 测定竹炭对甲醛蒸气的吸附量, 研究了吸附量与温度及时间的关 系,并探讨了竹炭对甲醛的吸附和脱附机理, 提出一种竹炭对甲醛吸附的测定方 结合竹炭 的 SEM 照片,考察了竹炭粉的粒度对甲醛吸附量的影响结果表明:在 55 3 h 的吸附条件 Y NG L 下,竹炭对甲醛蒸气的吸附量最大, 达 68. 5mg/g;竹炭粉的粒径对甲醛的吸附量的影响不太显 著, 这主要由竹炭本身的微观结构决定的; 竹炭对甲醛的吸附主要是物理吸附,在脱附过程中,其甲醛余量与 时间的关系符合 y= 109. 19x- 1. 1084, 相关系数 r= 0. 979 4 : 竹炭; 甲醛 : TQ424. 19 : : 0253- 2417( 2005) 01- 0077- 04 STUDY ON DSORPTION OF FORM LDEHYDE BY B MBOO CH RCO L Y NG Lei, CHEN Qing-song, L I Shou-lian, LIXiao-yan, YE Gu-i zu (College of Chem istry andM aterialScience, FujianN ormal University, Fuzhou 350007, China) A bstrac t: mount of formaldehyde vapor adsorbed by bamboo charcoalwas determ ined by spectrophotometry and the relations among adsorption amount, tmi e and temperaturewere studied. Furthermore, the mechanism of formaldehyde adsorption and desorption on bamboo charcoalwas discussed and the measuring method of formaldehyde adsorption was established. From SEM pictures of bamboo charcoa,l the influence of particle size on amount of formaldehyde adsorptionwas investigated. The results showed that, under the adsorption condition of 55 and 3 h, the adsorption amount of formaldehyde on bamboo charcoalwasmax mi al, up to 68. 5mg/g. Bamboo charcoal particle size has some effects on amount of formaldehyde adsorption but not obvious, which is mainly caused by its m icrostructure. The adsorption ismainly physisorption, so th