等离子体电解氧化膜的工艺优化及耐腐蚀性能评价.pdfVIP

等离子体电解氧化膜的工艺优化及耐腐蚀性能评价 彭家志，﹡陈砺，王红林，严宗诚，王丽 （华南理工大学化学与化工学院广东省绿色化学产品技术重点实验室 广东 广州 510640） 摘 要：研究了镁合金等离子体电解氧化膜的表面制备工艺。采用正交设计法优化实验方案， 对每个方案制备的氧化膜的硬度和耐点滴腐蚀时间进行分析。确定各因素对氧化膜性能的影 响程度，优化工艺配方。在较优的工艺配方条件下研究了电极距离及电解液体积对膜表面形 貌的影响。并采用SEM，XRD 等测试手段对较优工艺条件下制得的样品进行表征，发现制 得的膜表面呈现“火山口”形貌，其主要由MgSiO3 和镁橄榄石的Mg2SiO4 晶相物质组成。 对制备的样品及AZ31 镁合金进行动电位极化曲线测试，结果表明经过等离子体电解氧化处 理的试样的耐腐蚀性能得到改善。 关键词：等离子体电解氧化；镁合金；动电位极化 中图分类号：TG174.451 文献标识码：A The Optimization of Plasma Electrolytic Oxidation Process and Corrosion Performances of its Oxidation Films WANG Li, CHEN Li, WANG Honglin, YAN Zongcheng, PENG Jiazhi (School of Chemistry Chemical Engineering, South China Univ. of Tech. , Guangdong Provincial Laboratory of Green Chemical Technology, Guangzhou 510640, Guangdong China) Abstract: The orthogonal design was used to select the optimized plasma electrolytic oxidation process parameters. The microhardness and the time of dropping corrosion test of each plasma electrolytic oxidation film were examined to evaluate the influence of each factor. The effect of electrode distance and the volume of electrolyte on the surface morphology were also investigated. The micorstructure and composition of the films made in the optimization conditions were also investigated. The potentiodynamic polarization curves were employed to evaluate the corrosion resistance of AZ31 magnesium alloy and plasma electrolytic oxidation films. The results showed that the ceramic films were composed of MgSiO3 、Mg2SiO4 The uniform corrosion resistance could be enhanced considerably after plasma electrolytic oxidation(PEO) treatment. Keywords: plasma electrolytic oxidation; magnesium alloy; potentiodynamic polarization; impedance spectroscopy 1 作者简介：彭家志（1985－）, 男, 硕士研究生. 主要从事绿色化学与可再生资源研究. ﹡通讯作者：陈砺, 教授, 博士生导师. E-mail: celichen@mail.scut.edu.cn 0 引言 等离子体电解氧化(Plasma electrolytic oxidation, PEO)是近年兴起的一种在铝、镁、钛 等 轻金属及其合金表面原位生长陶瓷氧化膜的新技术[1-3]。它与其他许多表面处理技术，尤其 是与阳极氧化技术相比有许多优越性，如电解液无铬无磷、膜层硬度高