氯盐对水泥基材料硫酸盐侵蚀破坏的影响_刘加平.pdfVIP

网络出版时间：2016-09-18 10:15:35 网络出版地址：/kcms/detail/31.1764.TU1015.046.html 1 氯盐对水泥基材料硫酸盐侵蚀破坏的影响 1 1 2 2 刘加平 ，刘玉静 ，石亮 ，穆松 （1.  东南大学材料科学与工程学院，南京 210096 ；2. 江苏苏博特新材料股份有限公司，南京 211103 ）  摘要：研究了氯盐对水泥基材料硫酸盐侵蚀破坏的影响。侵蚀过程中试件的质量变化与膨胀率之间呈现指 数关系，氯盐降低了硫酸盐侵蚀过程中侵入物质引发膨胀破坏的可能性。主要原因在于：氯盐能够抑制硫 酸根离子向试件内部的传输，同时削弱了硫酸根离子的化学结合能力，进而降低了膨胀性腐蚀产物的生成 量，氯盐优先生成的 Friedel’s 盐填充孔隙，引发孔径的细化，进一步限制了硫酸根离子参与反应的能力。  关键词：硫酸盐-氯盐；水泥基材料；离子传输；腐蚀反应；孔结构 Effects of Chloride on Sulfate Attack of Cement- Based Materials 1 1 2 2 LIU Jiaping , LIU Yujing , SHI Liang , MU Song (1.College of Materials Science and Engineering, Southeast University, Nanjing, 210096;  2. Jiangsu Sobute New Materials Co.,Ltd, Nanjing,211103,China) Abstract ：The effects of chloride on sulfate attack of cement-based materials were investigated. The results show that, the mass change and expansion of specimens in the process of sulfate attack satisfy exponential relationship. Chloride can weaken the expansion damage of invasion materials. The main reasons are as follows: Chloride can inhibit transmission of sulfate; meanwhile the chemical combination of sulfate ions can also be weakened, as a result of the decrease in the contents of the corrosion products. Simultaneously, the preferential generation of Friedel’s salt by the r