封闭体系中水溶液导电行为随时间变化规律的研究-上海有机化学研究所.pdfVIP

2002 年第 60 卷 化 学 学 报 Vol. 60 , 2002 第 9 期 , 1619～1623 ACTA CHIMICA SINICA No. 9 , 1619 ～1623 封闭体系中水溶液导电行为随时间变化规律的研究 鲁传华 　　贾　勇　　李　全　　张菊生 (安徽中医学院药学系 　合肥 230038) 摘要 　 在封闭体系中 ,较大的时间尺度上二次水及 NaCl , HOAc , C H N ,苦味酸等溶液电导率在确定的温度下不再 5 5 是恒定值 ,表现出持续变化. 变化轨迹可分为电导率随时间增加而增大的水型轨迹和随时间增加而减小的吡啶型轨 迹两种类型. 对比实验表明产生这两类导电轨迹的原因是由于物质对水的结构有促进能力和破坏能力两种不同功 能所造成 ;而电导率持续变化的原因则可能与自然环境某些电磁辐射场强度的持续变化有关连. 关键词 　水溶液 , 电导率,时间 Study on Conductivity Change of Aqueous Solutions over Time in Closed System LU , ChuanHua 　　J IA , Yong 　　LI , Quan 　　ZHANG, JuSheng ( ) Pharmaceutical Department of Chinese Traditional Medical College of Anhui , Hefei 230038 Abstract 　In this paper , the conductivities of doubledistilled water and aqueous solutions of NaCl , HOAc , C H N , etc . were determined in an elongated time period. It is found that the conductivity values of the 5 5 solutions at certain temperature are not constant and change over time. On a large time scale , the variation trajectories can be divided into two groups. The one is that the conductivities increase with time increase , known as “water type trajectory ”; and in the other the conductivities decrease with time increase , known as “pyridine type trajectory ”. Contrast experiments showed that the “water type trajectory ”would be obtained with the promote