一种纳米纯agi气溶胶的制备方法及其成冰核效率的检测-气象.pdfVIP

一种纳米纯AgI 气溶胶的制备方法及其成冰核效率的检测1 杨绍忠 陈跃 （中国气象局人工影响天气中心，北京，100081） 提要：将100mg 纯AgI 粉末置于一个气氛炉的汽化管内加热到1600℃使之汽化，再利用高 3 压空气将气态AgI 爆冲到一个容积为2m 的金属容器里，骤冷后形成AgI 气溶胶。用碳支持 膜对形成的AgI 气溶胶粒子自然沉降取样，然后用X 射线衍射仪和电镜检测其成分和粒子尺 度。检测表明：粉末状纯AgI 经汽化-冷凝产生的气溶胶其成分仍为纯AgI，粒子尺度在0.84～ 34.6nm，峰值直径约为2.17nm。为了验证产生的纳米纯AgI 气溶胶在冰核化中是否具有成 冰核活性，用15L 混合云室分别在云室中有冷雾和无冷雾两种条件下定量注入纳米纯AgI 气溶胶，检测了它们在不同温度下的成冰核效率，检测结果是：在云室中有-10℃冷雾时， 11 10 成冰核效率为1.1×10 个/g.AgI，在云室中-10℃无冷雾时，成冰核效率约为3.4×10 个 /g.AgI。 关键词：AgI 汽化-冷凝 气溶胶 成冰核效率检测 Preparation of pure AgI nano-aerosol and laboratory test of its ice nucleation efficiency Yang shaozhong Chen yue （Weather Modification Center of China Meteorological Administration, Beijing, 100081） Abstract : 100 milligram pure silver powder is placed in a vaporization tube of an electrical heating furnace and heated to 1600 ℃ for gasification. The high-pressure air then burst the gaseous AgI into a 2m3 metal container and AgI aerosols are formed after suddenly cooled afterward. AgI aerosols are sampled by natural sedimentation using the Formvar stabilized with carbon support films . The results indicate that the aerosol composition maintain pure AgI and the size spectrum width is 0.84～34.6nm with 2.17nm peak in diameter. The ice nucleation efficiency of the quantitative pure AgI aerosol is detected by a 15-liter mixed cloud chamber, with and without fog, respectively. The preliminary results is that the efficiency of ice nucleation is about 1.1 ×1011 /g·AgI under the condition of -10℃with cold fog, and 3.4 ×1010 /g·AgI without cold fog. Key words: AgI vaporization-condensation aerosol ice nucleation detection 1 国家自然科学基金资助项目：纳米碘化银在冰核化中纳米效应的实验研究 （4117512