乙烯裂解炉管结焦机理及其防护措施研究进展-中国腐蚀与防护学报.PDFVIP

第29 卷 第5 期 腐蚀科学与防护技术腐蚀科学与防护技术 Vol. 29 No. 5 2017 年9 月 CORROSION SCIENCE AND PROTECTION TECHNOLOGY Sep. 2017 乙烯裂解炉管结焦机理及其防护措施研究进展 孙孝儒 沈利民 中国矿业大学化工学院 徐州 221116 摘要 介绍了乙烯裂解炉炉管催化结焦、自由基结焦和气相结焦的3 种结焦机理以及近年来国内外结焦抑制 技术的发展情况，并对如何改善裂解原料和炉管材料、优化裂解工艺和结构、使用结焦抑制剂以及表面涂层等 技术进行了详细介绍。最后，对如何减少结焦情况和提高炉管使用寿命提出了相关建议，综合运用多种抑制 结焦的措施能够有效地减少结焦量，如涂层技术与冶金技术相结合，涂层技术与优化裂解原料相结合等。这 对于乙烯裂解炉管的现场生产操作具有一定的参考价值。 关键词 乙烯裂解炉 炉管 结焦机理 结焦防护 中图分类号 TG 174 文章编号 1002-6495(2017)05-0575-06 Research Progress of Coking Mechanism and Prevention Measures for Ethylene Cracking Furnace Tubes SUN Xiaoru, SHEN Limin School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou 221116, China Correspondent: SHEN Limin, E-mail: shenlm@cumt.edu.cn Supported by National Natural Science Foundation of China , Fundamental Research Funds for Central Universities (2013QNA15) and Jiangsu Science and Technology Support Program (BE2013038) Manuscript received 2017-03-01, in revised form 2017-07-27 ABSTRACT The known coking mechanisms of ethylene cracking furnace tubes are introduced such as catalytic coking, free radical coking and gas coking. Then, the development of coking-prevention tech- nology at home and abroad is summarized, such as the improvement of the cracking material and the fur- nace tube material, the optimization of cracking process and structure of cracking unit, the application of coking-inhibitor and surface coating etc. Finally, suggestions are made on relievin