烤烟型卷烟主流烟气中烟碱_游离烟碱的量对感官舒适性的影响.pdfVIP

工艺技术 烤烟型卷烟主流烟气中烟碱、游离烟碱的量对感官 舒适性的影响 1, 2 2 2 2 2 2 王明锋 ，曾晓鹰 ，李先毅 ，廖头根 ，朱保昆 ，夏建军 1.云南大学化学科学与工程学院 (昆明 650091；2.红云红河烟草(集团)有限责任公司技术中心 (昆明 650202) 摘 要 研究建立卷烟主流烟气中总烟碱、游离烟碱的超高效液相色谱的分析方法。采用含正庚基磺 酸钠为离子对试剂的三氟乙酸水溶液及乙腈为流动相，BEH C18 色谱柱进行色谱分析。方法的相关系数 2 R ≥0.999，烟碱回收率(96.6~103.7)%，方法的RSD为(0.80~1.20)%。对50种单体原料烟主流烟气中总烟碱 和游离烟碱进行检测和感官评吸，采用统计产品与服务解决方案(SPSS)和Matlab软件对上述卷烟主流烟气 中总烟碱、游离烟碱与感官舒适性的影响进行相应研究。结果表明：烤烟型卷烟中总烟碱和游离烟碱含 量与卷烟劲头都呈现了高度的正相关性，而游离烟碱的含量与感官舒适性的影响呈现高度的负相关性， 但总烟碱的含量与感官舒适性无明显相关性。 关键词 游离烟碱；烟碱；分析；感官舒适度 Effects of Total Nicotine and Free-base Nicotine Content in Virginia Type Cigarette Smoke on Sensory Coziness 1, 2 2 2 2 2 2 Wang Ming-feng , Zeng Xiao-ying ，Li Xian-yi ，Liao Tou-gen ，Zhu Bao-kun ，Xia Jian-jun 1.School of Chemical Science and Technology, Yunnan University (Kunming 650091)； 2.RD Center of Hongyunhonghe Tobacco Group (Kunming 650202) Abstract A ultra high performance liquid chromatographic method was developed for determination of total nicotine and free-base nicotine in cigarette Main Stream Smoke(MSS), mobile phase was consisted of acetonitrile and trifluoroacetic acid aqueous in which heptanesulfonate buffer act as an ion pair agent. BEH C18 column was employed in experiments. The Correlation was higher than 0.999, the recovery values obtained were in the 96.6%~103.7% range. The RSD values were in the range 0.80%~1.20% for total nicotine. Total nicotine, free-base nicotine and sensory quality were determined in 60 kinds of tobacco leaf raw material. Statistical products and service solutions (SPSS) and Matlab were employed in correlation analysis between nicotine content in virginia type ciga