Ce3+掺杂聚苯胺中空微球环氧涂层防腐蚀研究.docVIP

Ce3+掺杂聚苯胺中空微球/环氧涂层防腐蚀研究 李芝华 胡建康 李彦博 郑峰 刘军 中南大学材料科学与工程学院 X 关注成功！ 加关注后您将方便地在 我的关注中得到本文献的被引频次变化的通知！ 新浪微博 腾讯微博 人人网 开心网 豆瓣网 网易微博 摘????要： 聚苯胺作为一种新型的防腐蚀材料, 在钢铁防腐蚀领域具有良好的应用前景。通过自组装法在聚 (2-丙烯酰胺基-2-甲基丙磺酸) (PAMPS) 水溶液中制备了聚苯胺 (PANI) 中空微球, 将稀土Ce3+掺杂到聚苯胺中空微球表面制备了一种新型的Ce3+掺杂修饰的聚苯胺中空微球 (PANI-Ce3+) 。以PANI-Ce3+中空微球为防腐填料添加到环氧树脂 (EP) 中, 制备Ce3+掺杂修饰的聚苯胺中空微球/环氧 (PANI-Ce3+/EP) 防腐涂层。采用FT-IR、UV-Vis、SEM、XRD等对PANI-Ce3+中空微球进行表征, 通过动电位极化法、交流阻抗测试探究PANI-Ce3+/EP涂层的防腐蚀性能。结果表明:PANI-Ce3+/EP涂层具有较高的腐蚀电压 (Ecorr=-0.414 V) 和较小的腐蚀电流密度 (Icorr=0.676×10-5μA/cm2) ;PANI-Ce3+/EP涂层低频区阻抗模量随浸泡时间呈现先减小后增大的变化趋势, 在质量分数3.5%的NaCl水溶液中经过1 680 h腐蚀后, 阻抗模量保持在106.6?cm2;表面有划伤的PANI-Ce3+/EP涂层在质量分数3.5%的NaCl水溶液进行1 680 h腐蚀实验后, 涂层表面不起泡, 仅在划痕处有少量铁锈。PANI-Ce3+/EP涂层表现出优异的耐腐蚀性能。 关键词： 聚苯胺中空微球; Ce3+掺杂; 涂层; 耐腐蚀性能; 自组装法; 作者简介：李芝华 (1963—) , 男, 教授, 博士生导师, E-mail:ligfz@mail.csu.edu.cn. 收稿日期：2017-06-07 基金：国家自然科学基金资助项目 Anticorrosion study of epoxy coating with Ce3+ doped polyaniline hollow microspheres LI Zhihua HU Jiankang LI Yanbo ZHENG Feng LIU Jun School of Materials Science and Engineering, Central South University; Abstract： As a novel anticorrosion material, polyaniline (PANI) has good application prospect in the field of steel anticorrosion. Polyaniline hollow microspheres were fabricated by self-assembly method in poly (2-acrylamido-2-methylpropanesulfonic acid) (PAMPS) aqueous solution. After that, cerium ions were loaded onto polyaniline to prepare Ce3+doped PANI (PANI-Ce3+) hollow microspheres. PANI-Ce3+ hollow microspheres were employed as functional additives and dispersed in epoxy resin (EP) . Structure and morphology of PANI-Ce3+ hollow microspheres were characterized by Fourier transform infrared spectroscopy (FT-IR) , scanning electron microscopy (SEM) , X-ray diffraction (XRD) and Transmission electron microscopy (TEM) etc. Electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization test were employed to analyze anticorrosion performance of PANI-Ce3+/EP coatings explored in 3.5 wt% Na