二甲基二烯丙基氯化铵聚合物的研究现状及进展研究.pdfVIP

编号：D08 二甲基二烯丙基氯化铵聚合物的研究现状及进展 向 莹，刘全校，许文才，曹华，刘淑婧 （北京印刷学院印刷包装材料与技术北京市重点实验室,北京 102600） 摘要：二甲基二烯丙基氯化铵(DMDAAC)是一种水溶性阳离子型季铵盐，其均聚物和共聚物 都具有正电荷密度高、相对分子质量易于控制、高效价廉等优点，可广泛应用于油田、造 纸、水处理、医药和化妆品等领域，引起国内外普遍关注。介绍了DMDAAC聚合物的结构及 性质，综述了DMDAAC聚合物的合成方法、类型以及研究应用现状，并展望了今后的研究重 点和方向。 关键词：二甲基二烯丙基氯化铵；聚合物；聚合；应用 Current Status for Research and Advance of Dimethyldiallyl Ammonium Chlorides’ Polymers XIANG ying, LIU Quan-xiao, XU Wen-cai, CAO hua, LIU Shu-jing (Beijing Institute of Graphic Communication, Lab.of Printing Packaging Material and Technology-Beijing Area Major Laboratory, Beijing 102600) Abstract:Dimethyldiallyl ammonium chloride (DMDAAC) is a water -soluble cationic quaternary, its homo-and copolymer all have high positive charge density, their molecular weight can be controlled easily, and they are cheap and applied widely, such as in oilfields, papermaking, water -treament, medicine, cosmetics and etc., so a great deal of attention from home and abroad had been focussed on them. Structure and nature of dimethyldiallyl ammonium chlorides ’ polymers were described, the advances in the polymerization method of dimethyldiallyl ammonium chlorides ’polymers, types and current status for research and application of its polymers were summarized. Future emphases and directions of dimethyldia llyl ammonium chlorid’s polymers were discussed. Key words: dimethyldiallyl ammonium chloride; polymer; polymerization; applications [1-6] 在当今造纸、水处理、纺织印染、医药、皮革和化妆品等领域 中，水溶性阳离子单 体二甲基二烯基氯化铵(DMDAAC) 的贡献是不可低估的。由于DMDAAC 是一种含有两个 不饱和键的季铵盐，其通过均聚或与其它单体共聚形成阳离子型聚合物，具有正电荷密度 高、水溶性好、相对分子质量易于控制、高效无毒、造价低廉等优点，因此有着广泛用途 和发展前景。国外的研究者从50年代开始就对其单体合成提纯、聚合方式、聚合反应动力 学及机理、聚合物结构和分子量与产品性能之间的关系等，进行了大量的研究，并已实现 作者简