第2讲 微晶玻璃.pptVIP

* 4.7 Preparation of transparent lithium-mica glass-ceramics Mica glass-ceramics are the typical machinable ceramics. The machinability is originated in the cleavage of mica crystals and the interlocking structure formed by the flakelike mica crystals. Li-type taeniolite带云母 (LiMg2Li-Si4O10F2) Li-phlogopite 金云母(LiMg3AlSi3O10F2) Heat Resistance Exceeding 800℃, Electrical Insulating Properties, High Mechanical Strength Precision Electrical Insulators, Vacuum Feedthroughs, 馈穿 Windows For Microwave-type Parts, Boundary Retainers（支架） on The Space Shuttle * Fig. 1. SEM photographs of polished and chemically etched surfaces of parent glasses: (a) LS150, (b) LS165 and (c) LS200 specimens. Process The mixtures were calcined at 900 ℃ for 1 h, melted in a sealed platinum container at 1450℃ for 2 h, and then cooled outside of the furnace. The obtained glasses were annealed at about 20℃ higher temperatures than their glass-transition temperatures shown in Table 1 and cooled at 2℃/min to eliminate strain. The parent glasses prepared by such a method were heated at 650–900 ℃ for 2–48 h to be crystallized. The heating rate was 10 ℃ /min. * Fig. 7. SEM photographs of polished and chemically etched surfaces of LS115 specimen heated at (a) 650℃for 2 h and (b) 700 ℃ for 2 h, LS150 specimen heated at (c) 650 ℃ for 2 h and (d) 700 ℃for 2 h, and LS200 specimen heated at (e) 650℃for 2 h and (f) 700 ℃for 2 h. * * * * Fig. 7. Charge–discharge curves at the 500th cycle of In/LiCoO2 cells with the 67Li2S·33PS2.5 (=80Li2S·20P2S5) glass-ceramic. The inset shows cycling performance of the rechargeable capacities and charge–discharge efficiencies for the cell under the current density of 64 μA cm?2. * BaO–CaO–Al2O3–SiO2 Glass–ceramic Sealants for Intermediate Temperature Solid Oxide Fuel Cell Application thermal expansion behavior, electrical resistivity, leak-rate, and shrinkage and flow behavior at the SOFC operating temperature (800 ℃). Applications : catalytic supports（催化剂载体）, membranes