北京大学 电分析 课件 扫描探针显微镜及其应用 elect8a.ppt

Schematic representation of the principles of SECM with micro-ITIES SECM image obtained using a micro-ITIES probe (5-?m tip) . Substrate was silicon with parallel platinum bands. J.Electroanal.Chem., 1997, 439, p137-143 Positive feedback Negative Feedback Approach a big L/L interface Approach a solid substrate RG = Rg/a Bard et al. have developed the theory for RG ? 10 cases. However, for micropipettes as the tips for SECM, the RGs are usually ? 2. Using software package PDEase (SPDE, Inc.), we have solved the theoretical i - d curves for RG ? 2. J.Phys.Chem B., 1998, 102, p9915-9921 RG =