温度及氧碳比对气化炉内颗粒物性质的影响.pdf

第31 卷 第5 期 中 国 电 机 工 程 学 报 Vol.31 No.5 Feb.15, 2011 58 2011 年2 月15 日 Proceedings of the CSEE ©2011 Chin.Soc.for Elec.Eng. 0258-8013 (2011) 05-0058-05 TQ 54 A 470 20 文章编号： 中图分类号： 文献标志码： 学科分类号： ⋅ 温度及氧碳比对气化炉内颗粒物性质的影响 祝庆瑞，郭庆华，廖胡，梁钦锋，于广锁 (煤气化教育部重点实验室(华东理工大学) ，上海市 徐汇区 200237) Effects of Temperature and Oxygen and Carbon Ratio on Particle Property in Gasifier ZHU Qingrui, GUO Qinghua, LIAO Hu, LIANG Qinfeng, YU Guangsuo (Key Laboratory of Coal Gasification (East China University of Science and Technology), Ministry of Education, Xuhui District, Shanghai 200237, China) ABSTRACT: On the laboratory scale opposed multi-burner 关键词：多喷嘴对置式气化炉; 水煤浆; 颗粒物; 温度; 氧 gasifier (OMBG), effects of temperature and oxygen and 碳比 carbon ratio on particle properties were studied, and the 0 引言 formation mechanism were investigated. The results show that, as temperature increases, there are more spherical particles and 煤炭气化技术，尤其是高压、大容量气流床气 concentration of S, Fe, Na and fine particles are higher on 化技术，是洁净煤技术的龙头和关键[1] 。煤在气化 particles surface. As oxygen and carbon ratio increases, 过程中不但生成目标产品合成气，同时还生成副产 proportion of particles increases and carbon content in particles 品颗粒物和熔渣。其中颗粒物由于比表面积很大， decreases. Oxygen and carbon ratio has little influence on concentration of S, Fe, Na, Al, Si on particles’ surface. Oxygen 很容易富集大量有毒的重金属元素(如铅、镉等) ， and carbon ratio has obvious influence on particle size 严重危害人类健康，同时造成环境污染[2-4] ；另外， distribution. When oxygen a