微波法制备有机改性膨润土及相变储热材料研究.pdfVIP

微波法制备有机改性膨润土及相变储热材料 1 2 龙娜 ,张正国 1 2 （ ， 华南理工大学传热强化与过程节能教育部重点实验室，广东 广州 510640 ） 摘要：利用微波法以十六烷基三甲基溴化铵和钠基膨润土为原料制得有机改型膨润土，将反应时间缩短到 1min，大大缩短了反应时间，降低了能耗。通过设计一组正交实验，考察了不同加热功率、固液比、加热 时间以及十六烷基三甲基溴化胺/膨润土质量比对改性膨润土 001 晶面间距值（d001 ）的影响，优化了制备 条件，制备出有机改性膨润土。通过XRD 分析表明膨润土的晶面距提高到3.29nm，通过红外光谱分析表 明十六烷基三甲基溴化铵已经成功地进入膨润土中。将微波法制得的有机改性膨润土与十八烷复合，发现 十八烷的含量较传统方法有了提高。 关键字：微波；膨润土；有机改性；相变储热材料 中图分类号：TU528 文献标识码：A 文章编号： Preparation of organically modified bentonite and phase change thermal enenagy storage materials by microwave method 1 2 Long Na , Zhang Zhengguo (1,2 Laboratory of Enhanced Heat Transfer and Energy Conversation , The Ministry of Education , South China University of Technology , Guangzhou 510640 ,Guangdong, China) Abstract : Using the hexadecyl trimethyl ammonium bromide and Na-bentonite as raw material, the organic bentonite was prepared by microwave method, which can shorten the reaction time, reduce energy consume. By designing the orthogonal experiment, the effects of the heating power, solid-liquid ratio, the time, the mass ratio of hexadecyl trimethyl ammonium bromide to Na-bentonite on crystal plane spacing of modified bentonite were discussed, and the best condition of each reaction was determined. With the optimize condition, the modified bentonite was prepared. The crystal plane spacing of modified bentonite increased to 3.29nm by X-ray diffraction. The results of infrared spectrum indicates that hexadecyl trimethyl ammonium bromide has enter the interlayer of bentonite. The content of octadecane in modifi