碳纳米管与PVA协同加强光谱探针并应用于灵敏测定肝素钠研究.pdfVIP

碳纳米臀与PVA协同加强光谱探针弗应用于灵敏测定肝素钠 257 碳纳米管与PVA协同加强光谱探针并 应用于灵敏测定肝素钠 ProbeBasedonthe EffectofCarbon EnhancingSpectral Synergic NanotubesandPVAfortheSensitiveDeterminationofHeparin 官杰，王宗花，孙锈泉，张菲菲，夏延致 (青岛大学国家培育慕地一纤维新材料与现代纺织重点实验室，山东青岛266071) GUAN Yan—zhi Jie，WANG Fei—fei，XIA Zong-hua，SUNXi—quan，ZHANG ofFiberMaterialsandModernTextile，the Base (Laboratory Growing State for KeyLaboratory，QingdaoUniversity，Qingdao 摘要：提出将碳纳米管(CNTs)作为一种新型分析增效试剂用予加强光谱探针，研究了其与水溶性大分子增效试剂聚乙 X 10‘L·tool。· 蓬嚣痣每△矗残正院，鋈努方翟先嫩=一0．006◆0．360C(rag／L)，表露糍尔暖光系数￡一4。29 clrl_‘，R=0．9991。在最佳实验条件下，对肝索钠注射液效价进行了测定。 关键调：碳纳米管，忍基紫；光谱探针；肝素钠；协同加强 中凰分类号：0657．32文献标识鹤：A 文章编号：1001-4381(2008)10—0257一04 Abstract：Thecarbonnanotubes(CNTs)wereasanovelkindof to regarded enhancingagentimprove theeffectof anovel methodwiththe effectof spectralprobe。andfadingspectrophotometricsynergic CNTsandPVAforthedeterminationof with Violet(EV)isinthe Hep Ethyl proposedpresentpa— mechanismofthe effectofCNTsandPVAwasdiscussedinthiswork。Theionas- per。The synergic sociation of andEVnoncovalentedwithCNTs complexHep through矿stacking，thehydrophilie ofwhichwas inthe of showed presencePVA．Comparativee