基于20.1万吨年聚氯乙烯悬浮聚合汽提工艺进行设计---.docxVIP

目录摘要IAbstractII第一章文献综述11.1聚氯乙烯的性质11.2聚合工艺实践方法11.3聚合生产工艺的两种操作方法的比较41.4国内外聚氯乙烯悬浮聚合的工艺进展51.5电石法聚氯乙烯生产工艺流程及PVC生产的绿化81.6汽提塔的操作关键141.7国内外聚氯乙烯的市场与生产状况17第二章工艺流程说明202.1乙炔发生工段工艺流程202.2氯乙烯合成工段工艺流程202.3聚合工段生产工艺流程212.4料浆汽提工段工艺流程222.5离心干燥工段工艺流程22第三章物料衡算243.1物料衡算依据243.2物料衡算条件243.3各个设备物料衡算263.4物料衡算总平衡37第四章热量衡算404.1乙炔发生器的热量衡算404.2聚合釜热量衡算424.3汽提塔热量衡算464.4气流干燥塔热量衡算464.5空气加热器热量衡算46第五章设备选型计算465.1聚合釜的选型465.2料浆排放槽的选型465.3汽提塔的选型465.4离心机的选型465.5气流干燥塔鼓风机的选型465.6 聚合反应的设备一览表46第六章聚氯乙烯树脂生产产生的污染及其治理466.1乙炔工段产生的污染及其治理466.2氯乙烯合成工段的污染及其治理466.3聚合工段的污染及其治理46总结46致谢46参考文献46摘要本文讲述了国内外聚氯乙烯工业生产技术的发展进程和目前状况，包括工艺流程、聚合方法等。本设计对20.1万吨/年聚氯乙烯悬浮聚合汽提工艺进行设计，主要对乙炔发生工艺、氯乙烯合成工艺、聚合生产工艺、汽提工艺、离心干燥工艺五大工艺过程进行了物料衡算、热量衡算和设备计算和选型三个方面的准确工艺计算。得出本次设计需采用九个70m3（Ⅱ型）不锈钢聚合釜并联操作，七台70m3出料槽，十三台WL-630型离心机。同时绘制了整工艺流程图、PVC聚合工段工艺流程图、聚合工段主要设备平面、立面布置图、PVC汽提工艺流程图、厂区平面布置图、以及聚合釜和汽提塔装配图等。关键词：聚氯乙烯悬浮法汽提工艺物料衡算热量衡算AbstractThis article describes the development process of domestic PVC industrial production technology and the current situation, including the process, polymerization methods. This design uses calcium carbide, suspension polymerization produce PVC. An annual output of 201,000 tons of polyvinyl chloride (PVC) whole section process design, the main process of acetylene, vinyl chloride synthesis, polymerization production processes, stripping process, centrifugal drying process conducted five process material balance, heat balance process equipment and accurate calculation and selection of the three aspects of computing base. This design requires the use of derived seven 70m3 (Ⅱtype) stainless steel polymerization reactor operated in parallel, seven 70m3 discharge chute, thirteen WL-630 centrifuge. While drawing the whole process flow diagram, PVC polymerization process flow diagram section, major equipment polymerization section plane, elevation layout, PVC stripping process flow diagram with control points, the factory floor plan, as well as the polymerization reactor and stripper assembly maps.Keywords: PVC suspension stripping process mat