本科毕业论文-掺杂对Li3V2(PO4)3正极材料电化学性能的影响.docVIP

本科毕业设计（论文） 掺杂对Li3V2(PO4)3正极材料电化学性能的影响 燕 山 大 学 2009年 6 月 本科毕业设计（论文） 掺杂对Li3V2(PO4)3正极材料电化学性能的影响 学院（系）：环境与化学工程学院 专 业： 应 用 化 学 学生 姓名： 学 号： 050110020021 指导 教师： 邵 光 杰（教授） 答辩 日期： 2009年6月23日  摘 要 本实验通过碳热还原法，分别选用柠檬酸、蔗糖、酚醛树脂为碳源制备碳包覆的锂离子电池正极材料Li3V2(PO4)3。经过XRD，SEM分析，三种碳源制备出的Li3V2(PO4)3样品都属于单斜晶型，结合电化学性能综合测试，结果显示10%的酚醛树脂表现出最佳的包覆效果，在3.0-4.3V之间首次充放电比容量达151.9mAh/g和138mAh/g，并在此基础上对Li3V2(PO4)3材料进行掺杂改性。在合成样品的原料中按照化学当量，分别添加不同含量的La2O3和Nb2O5合成掺杂相Li3V2(PO4)3。经过XRD分析发现：掺杂并没有改变Li3V2(PO4)3样品的晶体结构。通过充放电、循环伏安测试分析：当x=0.06时，样品即Li2.76(V0.94Nb0.06)2(PO4)3和Li3(V0.94La0.06)2(PO4)3达到最优的掺杂效果。用C/10电流在3.0-4.3V之间对电池进行充放电时，首次充放电比容量分别达到：154.4mAh/g、122.1mAh/g和137mAh/g、127.7mAh/g。 关键词　锂离子电池；正极材料；Li3V2(PO4)3；碳源；碳包覆；掺杂 Abstract In the study, the lithium-ion battery cathode materials Li3V2(PO4)3 were synthesized by carbothermal reduction method, with different carbon sources, including citric acid, sucrose and phenolic resin. Characterized by XRD, SEM, the crystal structures of all the resultant samples exhibited monoclinic type. Combined with the integrated electrochemical performance testing, the results showed that carbon coated Li3V2(PO4)3 sample which was synthesized by 10% of the phenolic resin as carbon source displayed the best performance.The initial charge-discharge capacity reached 151.9mAh/g and 138mAh/g with the charge-discharge current of C/10 in the voltage range of 3.0-4.3V. According that, the substituted Li3V2(PO4)3 samples were prepared by doping La2O3 and Nb2O5 with different contents, respectively. The crystal structures and the electrochemical performances of the doped samples were investigated by XRD, charge-discharge and cyclic voltammetry test. The results presented that there was no change in crystal structures compared with pure material of Li3V2(PO4)3. As x=0.06, the substituted samples, Li2.76(V0.94Nb0.06)2(PO4