硼铝硅系透明玻璃陶瓷晶粒生长动力学研究.docx

第 38卷增刊人工晶体学报Vol. 38 SpecialEdition2009年8月JOURNAL OF SYNTHET IC CRYSTALSAugust,2009硼铝硅系透明玻璃陶瓷晶粒生长动力学研究侯朝霞1,苏春辉2,王少洪1,陆浩然1,杨鸣春1,付仲超1,孙斌1( 1. 沈阳大学先进材料制备技术重点实验室 ,沈阳 110044; 2. 长春理工大学材料与环境工程学院 ,长春 130022)摘要 :采用熔融和两步热处理技术制备出 B2 O3 2A l2 O3 2SiO2 2ZnO 2L i2 O 2K2 O系透明玻璃陶瓷。硼铝硅系透明玻璃陶瓷晶粒生长动力学服从 JMAK方程 。用分形子谱维数分析了分形结构扩散控制晶体生长动力学过程,揭示了其与经典 化学反应动力学的不同 ,得出了反应动力学与分形结构的关系 ,通过实验数据拟合出分形子谱维数 dS为 1.2688。结 果表明用分形结构扩散控制反应动力学理论来分析硼铝硅系透明玻璃陶瓷的晶化过程是行之有效的。关键词 :透明玻璃陶瓷 ;硼铝硅 ;动力学;分形中图分类号 : TQ171;TB321文献标识码 :A文章编号 : ( 2009)S120224205Study on K inetics of Crysta l Growth in Tran sparen t BoronA lum inosilica te G la ss2ceramicsHOU Zhao2x ia1 , SU Chun2hu i2 , WANG Shao2hong1 , LU Hao2ran1 , YANG M ing2chun1 ,FU Zhong2chao1 , SUN Bin1( 1. Key Laboratory of Advanced Materials Technology, Shenyang University, Shenyang 110044, China;2. School of Materials and Environment Engineering, Changchun University of Science and Technology, Changchun, 130022, China)Abstract: Transp arent glass2ceram ics with B2 O3 2A l2 O3 2SiO2 2ZnO 2L i2 O 2K2 O ( BAS ) systemweresynthesizedbymeltingmethodandtwo2stepheat2treatedtechnique.Themechanismofthecrystalgraingrown in tran sparent BAS glass2ceram ics system was subm itted to JMA K function. The kinetics ofcrystalphase grow th contro lled by the diffusion in fractal structure was researched by fractal spectrum dimension.It was p resented that the difference between the fractal kinetics and traditional kinetics, andtherelationship between the reaction kinetics and fractal structure aswell. The fractal sp ectrum dim ension dSis 1. 2688 calculated by fitting curve of experim ental data. It was concluded that it was effectiveto analyze the crystallization behavio r of BAS transparen t glass2ceram ics by means of the kinetics ofdiffusioncontro l in fractalstructure.Key words: transparent glass2ceram ics; bo ron alum inosilicate; kinetics;fractal1引言玻璃陶瓷主晶相的析出是一非平衡过程,从动力学角度来看,析晶过程可分为成核、生长两