聚乙烯_水滑石复合材料的结构及其热降解行为.docxVIP

聚 乙 烯 / 水滑石复合材料的结构及其热降解行为 韩志东1 ， 王玥1 ， 赖文伟1 ， 姜丽1 ， 崔冰冰1 ， 崔久德2 ， 刘尚勇3( 1． 哈尔滨理工大学 材料科学与工程学院，黑龙江 哈尔滨 150040; 2． 江苏亨通线缆科技有限公司，江苏 吴江 215234;3． 广东电网公司佛山供电局，广东 佛山 528000)摘 要: 为了研究聚乙烯 /水滑石( PE /LDH) 复合材料的制备方法，利用重构法制备了十二烷基硫酸钠改性的水滑石( SDS － LDH) ，并以聚乙烯( PE) 为基体，以接枝聚乙烯( PEgMA) 为相容剂， 采用溶液法和熔融法制备 PE /PEgMA /SDS － LDHs 复合材料． 利用扫描电子显微镜( SEM) 、X － 射 线衍射( XＲD) 和热重分析( TGA) 技术分别研究了水滑石在基体中的分散情况、复合材料的结构及 不同制备方法对复合材料的热降解过程的影响． 研究表明: 采用熔融法和溶液法与熔融法相结合的 手段分别获得了微米复合材料 ( PE /PEgMA /SDS － LDH) 和纳米复合材料 ( PE /( PEgMA /SDS － LDH) ) ; 由于 SDS － LDH 的热分解温度较低，复合材料均表现出较低的初始热降解温度，相比于微 米复合材料，纳米复合材料表现出较高的热稳定性; 其最大热降解速率相应的温度及其热降解成炭 均有所提高．关键词: 水滑石; 聚乙烯; 复合材料; 纳米复合材料; 热降解中图分类号:TQ132. 2; TQ322. 2文献标志码: 文章编号:A1007－ 2683( 2013) 05－ 0001－ 05Structure and Thermal Degradation Behaviors of PE / LDH CompositesHAN Zhi-dong1 ， WANG Yue1 ， LAI Wen-wei1 ， JIANG Li1 ， CUI Bing-bing1 ， CUI Jiu-de2 ， LIU Shang-yong3( 1． School of Material Science and Engineering，Harbin University of Science and Technology，Harbin 150040，China; 2． Jiangsu HengtongCable Technology Limited Co． ，Wujiang 215234，China; 3． Guangdong Grid Co． Foshan Power Supply Bureau，Foshan 528000，China)Abstract: Mg-Al layered double hydroxide ( LDH) was modified with sodium dodecyl sulfate ( SDS) by regen-eration method． Polyethylene /modified LDH composites ( PE /SDS-LDH) were prepared by melt blending and solu- tion mixing method． Maleated polyethylene ( PEgMA) was used to improve the compatibility between LDH and PE． The structure and dispersion of LDHs in PE matrix were investigated by X-ray diffraction ( XＲD) and scanning e- lectron microscope ( SEM) ，respectively． Thermal degradation behaviors of PE /SDS-LDH composites were charac- terized by thermogravimetric analysis ( TGA) ． The results reveal that microcomposites ( PE /PEgMA /SDS-LDH) were obtained by melt blending method and nanocomposites ( PE /( PEgMA /SDS-LDH) ) were prepared by melt blending PE with master-batch of SDS-LDH and PEgMA obtained by solution mixing． Due to the ther