水样保存方法及保存时间对黄河水体中总有机碳测定的影响-河海期刊网.PDF

第30卷第6期 水摇 资摇 源摇 保摇 护 2014年11月 Vol.30 No.6 WATER RESOURCES PROTECTION Nov. 2014 DOI:10.3969/ j.issn.1004 6933.2014.06.014 水样保存方法及保存时间对黄河水体中 总有机碳测定的影响 郭摇 豪,温慧娜,宋庆国,穆伊舟 (黄河流域水环境监测中心,河南 郑州摇 450004) 摘要:水环境监测中,对于总有机碳的测量,国内外相关标准和规范对其水样保存条件缺乏统一要 求。 结合黄河水体的水质特点,重点选择pH值、保存时间、保存温度、前处理和水样浓度5 个方面 评估水样保存条件对总有机碳测试结果造成的影响。 结果表明,在采样后24h 内不能及时测试的 水样,必须改进保存方法,使水样的pH值小于2、水样运输及保存过程中以4益冷藏、样品测试前 充分混匀、避光密封保存。 关键词:总有机碳;水质样品;保存条件;黄河水体 中图分类号:X132摇 摇 摇 文献标志码:B摇 摇 摇 文章编号:1004 6933(2014)06 0067 04 Effects of preservation method and holding time of water samples on detection of total organic carbon (TOC) in Yellow River water GUO Hao,WEN Huina,SONG Qingguo,MU Yizhou (Water EnvironmentalMonitoring Center of Yellow River Basin,Zhengzhou450004,China) Abstract:In water environmental monitoring,there isno unified demandforwater sample preservation in termsof the detection of total organic carbon (TOC) according to related domestic and international standards. The effects of the water samples爷 preservation conditions,including the pH value,holding time,preservation temperature, pretreatment,and water sample concentration,on the detection of TOC were assessed based on the water quality characteristicsoftheYellow River. Theresultsshow that,ifthesamplescouldnotbetestedin24 hours,theyhave to be acidified to pH 臆2,refrigerated at 4益 in a refrigerator,homogenized in a blender before detection,and protected from light and atmospheric oxygen. Key words:total organic carbon (TOC);water samples;preservation conditions;Yellow River water 摇 摇 总有机碳(total organic carbon,TOC),表示溶解 技术规范,对水样的采集和保存条件进行了规范。 或悬浮在水中的有机物含碳量,以碳量表示水中有 美国环保署(EPA)对总有机碳测定中的水样保存方 机物总量的指标。 TOC 与 COD、BOD 、COD 相比 法及保存