剩余污泥燃料电池处理含铬废水的效能及机理 Efficacy and mechanism of microbial fuel cell treating Cr(VI)-containing wastewater with excess sludge as substrate.pdfVIP

中国环境科学 2014,34(9) ：2245~2251 China Environmental Science 剩余污泥燃料电池处理含铬废水的效能及机理 周秀秀 1,顾早立 1,郝小旋 1,张 姣 2,张志强 1*,夏四清 1 (1. 同济大学环境科学与工程学院,污染控制与资源化 国家重点实验室,上海 200092 ；2.上海城市管理职业技术学院,土木工程与交通学院,上海 200432) 摘要 ：采用剩余污泥为阳极底物,六价铬为阴极电子受体,构建双室微生物燃料电池(MFC).MFC 启动成功后,考察阳极室污泥初始浓度和阴 极室六价铬初始浓度对 MFC 产电性能及六价铬还原速率的影响.较高的污泥浓度(8~12g/L)对六价铬的还原速率影响均较小,且去除率均可 达 99% 以上.污泥浓度为 10g/L 的MFC 具有较高的产电性能, 内阻为 108Ω,最大功率密度输出为 3621mW/m3.阴极室较高的 Cr(VI)初始浓度 可维持较长时间的高输出电压,但对阳极污泥降解并无明显影响.XPS 测试结果表明,阴极 Cr(VI)的还原产物为 Cr(III),因电场作用被吸附在 电极片上,使得阴极溶液中的总铬浓度降低.研究表明,剩余污泥为底物的微生物燃料电池可以在产电的同时实现剩余污泥的资源化及电镀 废水的无害化. 关键词：微生物燃料电池；双室；剩余污泥；六价铬 中图分类号：X703.1 文献标识码：A 文章编号：1000-6923(2014)09-2245-07 Efficacy and mechanism of microbial fuel cell treating Cr(VI)-containing wastewater with excess sludge as 1 1 1 2 1,* 1 substrate. ZHOU Xiu-xiu , GU Zao-li , HAO Xiao-xuan , ZHANG Jiao , ZHANG Zhi-qiang , XIA Si-qing (1.State Key Laboratory of Pollution Control and Resource Reuse, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China ；2.School of Civil Engineering and Transportation, Shanghai Technical College of Urban Management, Shanghai 200432, China). China Environmental Science, 2014,34(9) ：2245~2251 Abstract ：The double-chamber microbial fuel cell systems (MFCs) were constructed with excess sludge as anodic substrate and potassium dichromate as catholyte. The effects of the initial concentrations of both excess sludge and Cr (VI) on MFC systems were investigated. According to the results, the MFC systems with sludge concentrations of 8~12 g/L presented almost the same degradation rates of Cr (VI), and a high removal efficiency of 99% was achieved. When the initial concentration of excess sludge was