卤水提钾技术研究进展+研究.pdfVIP

卤水提钾技术研究进展 * 李江涛，王静康 ，王永莉 (天津大学化工学院，天津300072，中国) 摘要：本文综述了国内外卤水提钾技术中研究进展，总结了化学沉淀法、萃取法、溶析法、膜分离法、冷分 解浮选法、热溶法、反浮选冷结晶法等相关工艺路线的原理及其优缺点，并结合该课题的具体特点详细介绍 了由天津大学国家工业结晶技术研究推广中心自主开发的冷却溶析结晶、反应萃取结晶两步新结晶工艺，再 经过洗涤干燥等一系列操作来制取粒度较大、纯度较高、符合国家一级标准的氯化钾产品，而且降低了能耗， 实现了经济成本的优化，为以后的工业化奠定了基础。 关键词：氯化钾；冷却溶析结晶；反应萃取结晶 Research advances in technology for extracting potassium chloride from brine LI Jiang-tao ，WANG Jing-kang ，WANG Yong-li （School of Chemical Engineering and Technology，Tianjin University，Tianjin 300072，China) Abstract: The research advance in technology for extracting potassium chloride from brine was reviewed. The principle ，advantages and disadvantages of the method of precipitation ，extraction ，solvent ，membrane ，cold decomposition-floatation ，heat dissolution and reverse floatation-cold crystallization were summarized. A new technology including two steps, namely a cooling-solvent crystallization process and a reaction-extraction crystallization process, developed by SRCICT according the characteristic of the task was introduced. Both the granularity and purity of the product are excellent enough to meet the industry standard of potassium chloride of the country through several farther processes such as washing and drying. The energy and material consumptions are much lower than the traditional technology. This work provides some data for the industrialization of the new technology. Key words: Potassium chloride; Cooling-solvent crystallization; Reaction-extraction crystallization * 收稿日期：2006-08-20 作者简介：王静康，1938 年出生，教授，e-mail ：hangtohua@163.com. 我国是一个农业大国，据调查全国 84%土地缺钾，2005 年按施肥比例 1：0.39：0.23 测算， 要求 K [1] 2O 产量达到 620 万吨，而目前国内实际产量