- 1、本文档共4页,可阅读全部内容。
- 2、原创力文档(book118)网站文档一经付费(服务费),不意味着购买了该文档的版权,仅供个人/单位学习、研究之用,不得用于商业用途,未经授权,严禁复制、发行、汇编、翻译或者网络传播等,侵权必究。
- 3、本站所有内容均由合作方或网友上传,本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺!文档内容仅供研究参考,付费前请自行鉴别。如您付费,意味着您自己接受本站规则且自行承担风险,本站不退款、不进行额外附加服务;查看《如何避免下载的几个坑》。如果您已付费下载过本站文档,您可以点击 这里二次下载。
- 4、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等,请点击“版权申诉”(推荐),也可以打举报电话:400-050-0827(电话支持时间:9:00-18:30)。
查看更多
Determination of Trace Copper (Ⅱ) in Water Samples by Kinetic-spectrophotometry
维普资讯
JournalofOceanUniversityofChMa (OceanicnadCoastalSeaResearch)
ISSN 1672—5182,Apnl30,2007,Vol6,No.2,PP.143-146
http.//www.ouc.edu.cn/xbywb/
E—mail.’xbywb ouc.edu.cn
DeterminationofTraceCopper(II)niWaterSamples
byKinetic--spectrophotometry
QIYanxia,JIHongwei,XINHuizhen,andLIULi
CollegeofChemistryandChemicalEngineering,KeyLaboratoryofMarineChemistryTheoryand
Technology,theMinistryofEducation,OceanUniversityofChina,Qingdao266100, R.China
(ReceivedJanuary18,2006;acceptedFebruary12,2007)
Abstract Anew kinetic.spectrophotometricmethodisproposedforhtedeterminationofcopper(II、.nlemehtodisbasedonhte
catalyticeffectofcopperfII1onhteoxidationofweakacidbrilliantbluedye(RAWL)bVhVdrogenperoxide.Thecopper(II)can
bedeterminedspectrophotometricallybymeastmnghtedecreaseofabsorbanceofRAM at :626l1m usnightefix-timemehtod.
nleoptimumreactionconditionsarcasofllows:pH720。buffersolutionNaOH—KH2PO4,RA、^厂I(200mgL)500mL,H2O,(30%)
0.50mL.reactiontemperature80℃ andreactiontime20mni nlelniearrna geofthismehtodisbe tween0IxgL nad l2IxgL na d
htelimitofdetectionis00l1u譬L。。,therelativestandarddeviation(RSD)nifivereplicatedetermniationsofr2nad8IxgL copper
(II)rac32%nad23%,respectivelyTwentyionsdonotniterferenihtedetemr niationofcopper(II).nlemehtodhasbene applied
satisfactorilytohtedetermniationofcopper(II)ni freshwatersamples(atpwaternadYellowRiverwaterfromLijni,Shnadong,
Chinaandseawatersamples(fromhteSouhtChinaSea),hterecoveryratesarc980%,1025%nad960%,respectively
Keywords copper;kinetic-spectrophotometry;caatlyticeffect;weakacidbrillinatbluedye(RAWL)
DOl10.10071sl1802-007-0143.1
Besides,htereraefew sutdiesusingthismehtodinsea
water.Inthissutdy,wesetupanew mehtodofrhtede-
1Introduction
文档评论(0)