负载型固体碱催化制备生物柴油研讨.pdf

负载型固体碱催化制备生物柴油研究 仲 鸣 周金能 肖国民 (东南大学化学化工学院．扛苏南京210096) 摘要：本文研究了壹裁型周体碱催化荆Kzcos／7一A1zn催化转基因大豆油酯交换矗应制备生物柴油的催化 活性，考察了催化荆用量、反应醇油比、反应温度、反应时问对反应的影响，确定了最优的反应条件。井考察了催 化荆活性组份负栽量、催化荆焙烧温度对催化活性的影响，确定了优化的催化剂制备书件。结果表明：在催化荆 负载量为3mmol／g时，蠛烧温度在650℃时，固体碱催化荆K。co，／7一Al±03具有很高的催化活性。在醇油比为 12：l，催化荆用量为大豆油的3％，反应温度为60一63℃．反应时间为3h，生物柴油的收丰达到90％以上。 关键词：田俸碱I酯史换}生靳柴油 STUDYoNPREPARATIoNOFB10DIESELCATALYZED BYLoADEDSoLID—BASE Guomin ZhongMing，ZhouJinneng，Xiao (The of andChemical CollegeChemistry Engineering， Southeast University，Nanjing，Jiangsu．210096) isa attractiverenewablefuelasit canbeusedin en— Abstract：Biodiesel particularly existing is from gines，isenvironmentallyfriendly，andreadilysynthesizedvegetableoils．Heterogene— OUS offer for theeconomicsofbiodiesel catalystsexcitingpossibilitiesimproving synthesis．In transesterificationof oilwithmethanolhasbeenstudiedina thiswork，the soybean heterogene— OUS aluminaloadedwith carbonateasasolidbase system，using potassium catalyst．Optimal conditionswere：massratioof to catalyst K2C03alumina0．041；calcinations preparation temper— for thereactionconditionsforthetransesterificationof ature。923K．A studyoptimizing soybean was the conditionsofreaction oil of60一63℃．reaction performe