上海市大气气溶胶中铅污染的综合研究 Comprehensive Study of Lead Pollution in Atmospheric Aerosol of Shanghai.pdfVIP

第27卷第5期 环 境 科 学 V01．27．No．5 2006年5月 ENVIRONMENTALSCIENCE May，2006 上海市大气气溶胶中铅污染的综合研究 山祖慈2 (1．中国科学院上海应用物理研究所，上海201800；2．上海市环境监测中心，上海200030) 汽车尾气是主要排放源，它们对气溶胶中铅的贡献率分别为50％、35％和15％． 关键词：大气气溶胶；PMlo；铅；同位素比；质子微探针；ICP—MS；EXAFS 中图分类号：x131．1；x831文献标识码：A文章编号：0250．3301(2006)05一0831．06 ofLeadPoHutionin Aerosolof ComprehensiVeStudy AtmosphericShanghai ZHANG Gui—linl，TAN Yuan—xunl，YUE Jian— Ming—guan91，LIXiao一1inl，ZHANG Wei—shen91，CHEN Zhu—c一 minl，WANGYin—son91，LIAi—gu01，LIYanl，ZHANGYuan—mao。，SHAN Instituteof Chinese of 201800 2． (1． Sciences， China；Shanghai Shanghai AppliedPhysics， Academy Shanghai 200030，China) M。nitoringCenter，Shanghai of Abstract：Theleadcontamination，leadandsource werestudiedacombinationseveral species assignment by analyticaltechniques suchasProton—induced emission (PIXE)，Proton coupled X-ray analysis microprobe(肛-PIXE)，Inductivelyplasma—mass extended fine Theresultsindicatethatthelead spectrometry(ICP—MS)andX—rayabsorptionstructure(EXAFS)techniques． concentrationintheairof decreasedoverthe1ast leadconcentrationof inthewinter Shanghaigradually years．Theatmospheric PMlo of2002was369 haddeclined28％in inthewinterof2003itdecreasedfurtherto237 ng·m一3，which by 2001，and ng·m一3．The majnlead inthe collectedinthewinterof2003were andPb0．TheSource was speciess