我国核能制氢技术分析研发进展.docVIP

我国核能制氢技术研究进展 张平，陈崧哲，王来军，徐景明 （清华大学 核能与新能源技术研究院，北京100084 摘要: 氢清洁能源，有非常好的应用前景以可持续的方式实现氢的大规模生产是实现氢的广泛利用的前提。核能制氢以来源丰富的水为原料，利用核能实现氢的大规模生产世界上许多国家，如美国、日本、法国拿大，都在大力开展核能制氢技术的研发工作。 关 键 词: 氢能；核能制氢；热化学循环； Development of Nuclear Production of Hydrogen in China ZHANG Ping，CHEN Songzhe, WANG Laijun, XU Jing-ming Institute of Nuclear and new energy technology (INET), Tsinghua University, Beijing 100084, China Abstract: Hydrogen is a promising clean secondary energy which needed to be produced from the primary energy. Nuclear hydrogen production, which generating hydrogen from water with nuclear energy, is considered as an efficient, greenhouse-free and massive hydrogen production. RD on the nuclear hydrogen production has been considerably conducted in many countries, including the United States, Japan, France, Canada, as well as in China. The researches was initiated in Tsinghua University since 2005, and the proof-of-concept experiments for the thermo-chemical iodine sulfur (IS) process and high temperature steam electrolysis (HTSE) were successfully carried out in 2009. Since 2010, the integrated lab scale facilities for the IS process and HTSE have been developed, the objective is to achieve the continuous stable operation of the two process with the hydrogen production rate of 100NL/h. In the paper, the RD plan of the nuclear hydrogen production program is presented, and the progress and the main results of the IS process is summarized. Key words: hydrogen energy; nuclear production of hydrogen; thermochemical cycle; progress 前言 传统化石燃料的有限储量和不可再生性以及其应用带来的温室效应等问题使清洁低碳能源研发受到重视。氢是无污染可再生的清洁能源，可储可输， 核能是清洁的一次能源，经过半个多世纪的发展，核电已经成为清洁、安全、成熟的发电技术。核能制氢（nuclear production of hydrogen）就是将核反应堆与采用先进制氢工艺的制氢厂耦合，进行氢的大规模生产。 我国已发展了居于第四代核能系统特征的高温气冷试验堆（HTR-10），高温堆示范电站的建设业已列入国家科技重大专项。作为高温堆工艺热应用的重要拓展，高温堆制氢技术的研究作为前瞻性研发课题得到重大专项的支持。清华大学核能与新能源技术研究院（INET）对核能制氢的两种主要工艺硫碘热化学循环和高温电解进行了大量基础研究，并成功进行了两种工艺的原理验证性实验[3]。目前正在进行集成实验室规模的台架研发。本文对INET核能制氢项目规划及碘硫热化学循环的进展进行了综述。 核能制氢研究计划 根据核能制氢研究工作的特点及国际上的研究进展，总体计划分为四个阶段：