交流阻抗谱(陈春华).pdfVIP

Chapter 11: AC Impedance Spectroscopy Introduction Basic elements in an electric circuit Nyquist and Bode plots Data analysis and software Examples Introduction Terminology: • AC Impedance Spectroscopy (IS) • Electrochemical Impedance Spectroscopy (EIS) • Complex Impedance Spectroscopy (CIS) References: • J.R. MacDonald, Impedance Spectroscopy, Chapel Hill, North Carolina, 1987. (John-Wiley, 2005?) • 史美伦，交流阻抗谱原理及应用，国防工业出 版社，2001. • 曹楚南, 张鉴清，电化学阻抗谱导论，科学出版 社，2002. Introduction Equivalent Circuit (EQUIVCRT.PAS) (DOS version) The 1st (??) powerful software for EIS analysis (V 3.96, May 1989-) for Johanna, Saskia and Hester. Bernard A. Boukamp “Mommy, what’s that stranger doing up in the attic room?” “Hush sweetheart, that’s your daddy. He is writing a big computer program.” Introduction -- This is a transient technique, but one that requires a general steady state condition. -- can be used for determining both: Interfacial parameters a) reaction rates b) rate constants c) capacitance/charge storage abilities d) diffusion coefficients e) adsorption rate constants f) reaction mechanisms And Material parameters a) conductivity b) dielectric constants c) bulk generation-recombination reaction rates d) charge mobilities e) film thickness f) equilibrium conc. of charged species g) presence of pores and cracks General concept -