煤热解与甲烷二氧化碳重整耦合制油过程研讨.pdfVIP

煤热解与甲烷二氧化碳重整耦合制油过程研究 刘佳禾，靳立军，王鹏飞，胡浩权* （大连理工大学化工学院，煤化工研究所；辽宁省大连市西岗区中山路 号 158 116012; hhu@chem.dlut.edu.cn，0411 摘要：本文研究了一种提高煤热解焦油产率的方法—煤热解与甲烷二氧化碳重 整耦合制油过程。实验在包含催化剂层和煤层的固定床反应器中进行。在 CH4 流量为400ml/min ，CH4 与CO2 的流量比为1:1，停留时间为30 min 的实验条件 下，考察了热解温度和煤的性质对焦油、水和半焦产率以及甲烷转化率的影响 规律。结果显示平朔煤在 CH4/CO2 气氛下热解的焦油产率最高，在热解温度为 750 oC 时的焦油、水、半焦产率和CH4 转化率分别为33.5、25.8 、69.5 wt.%和 25.3%, 焦油产率为相同条件下H2 和N2 气氛下热解的1.6 和1.8 倍。 关键词：煤；热解；甲烷CO2 重整；焦油 Integrated coal pyrolysis with CO reforming of 2 methane to improve tar yield Liu Jiahe ，Jin Lijun ，Wang Pengfei ，Hu Haoquan* （Institute of Coal Chemical Engineering, School of Chemical Engineering, Dalian University of Technology, 129 street, Dalian 116012, P.R. China, hhu@chem.dlut.edu.cn, 0411 Abstract: A novel integrated process of coal pyrolysis and CO2 reforming of methane for improving tar yield was carried out in a fixed-bed reactor consisting of upper catalyst layer and lower coal layer. The effect of pyrolysis temperature, coal properties on tar yield, water yield and CH4 conversion and effect of pyrolysis temperature on char yield were investigated at fixed conditions of 400 ml/min CH flow rate, 1:1 CH /CO ratio, 30 min 4 4 2 *作者简介：刘佳禾（1980–），男，辽宁省葫芦岛市人，博士研究生，主要从事煤化学方面的研 究。胡浩权，通讯作者，电话: +86-411E-mail: hhu@chem.dlut.edu.cn (Haoquan Hu) holding time. The results indicated that higher tar yield can be obtained when Pingshuo coal pyrolysis is integrated with CO2 reforming of methane. The tar, water, char yield and CH4 conversion are 33.5, 25.8, 69.5 wt.% and 25.3%, respectively, at the pyrolysis temperature of 750 °C. And the tar yield is 1.6 and 1.8 times as that in coal pyrolysis u