半间歇搅拌釜式乙氧基化反应器的数学模拟研究.pdfVIP

2008 年中国过程系统工程年会会议论文集 半间歇搅拌釜式乙氧基化反应器的数学模拟 安维中 1 李佳 1 董凤蕾 1 胡仰栋 1 刘兆滨 2 朱建民 2 ( 1. 中国海洋大学化工学院，山东 青岛 266100；2. 辽宁奥克化学集团，辽宁 辽阳 111003 ) 摘要：建立了工业半间歇搅拌釜式乙氧基化反应器的数学模型，包括反应动力学、汽液相平衡、汽液传质、反应体积的 变化和惰性气氮气的影响等。以 KOH 催化条件下乙二醇乙氧基化为例，通过数学模拟考察了环氧乙烷进料速率对反应 器操作的影响，得到优化的操作参数。在此基础上，模拟得到反应器中压力、环氧乙烷在汽液相中的组成及乙氧基化产 物随时间的分布，并同工业试验数据进行了比较。结果表明了模型的可靠性。 关键词：乙氧基化 半间歇反应器 模型 模拟 中图分类号：TQ223.24，TQ021.8 文献标识码：A Mathematics Simulation of Semi-batch Stirred Ethoxylation Reactor 1,2 1 1 1 2 2 An Weizhong , Li Jia , Dong Fenglei , Hu Yangdong , Liu Zhaobin , Zhu Jianmin (1. Department of Chemical Engineering, Ocean University of China, Qingdao, 266100, China; 2. Liaonin Oxiranchem Group, Liaoyang, 111003, China ) Abstract: The method of modeling industrially semi-batch stirred ethoxylation was developed by taking the kinetics, the vapor-liquid equilibrium, the vapor-liquid mass-transfer, the variation of reactive volume, as well as the effect of nitrogen on reactor into account. The method was illustrated by taking ethylene glycol ethoxylation process catalyzed by KOH as example. Based on the model, simulations were performed to investigate the effect of ethylene oxide (EO) feed flowrate on the reactor, so as to obtain the optimal and safe EO feed flowrate. The simulation results provided the typically dynamic profiles of the reactor pressure, the molar fraction of ethylene oxide in liquid and vapor, as well as the products composition. Simulation results were compared with the industrial experiment data, which showed the reliability of the developed mathematical model. Key words: Ethoxylation; Semi-batch reactor; Model; Simulation 引言