聚苯乙烯纳米纤维膜的PDMS功能化及润湿行为研究.docxVIP

毕业论文（设计）聚苯乙烯纳米纤维膜的PDMS功能化及润湿行为研究The Wetting Behavior Research of PDMS Functional Polystyrene Nanofiber Membrane学生姓名：指导教师：合作指导教师：专业名称：应用物理学所在学院：理学院2014年6月目 录摘要IAbstractII第一章前言11.1.静电纺纳米纤维膜技术原理11.1.1.静电纺复合纳米纤维膜实验装置11.1.2.静电纺丝装置技术现状与应用11.1.3.静电纺纳米纤维膜技术原理与发展方向21.2.超疏水表面制备方法21.3.本论文的主要研究工作31.4.本论文的构成4第二章本课题相关研究技术简介52.1.PDMS和PS的性质功能介绍52.1.1 PDMS和PS的基本性质介绍52.1.2 PDMS和PS的应用52.2.复合纤维膜的疏水性与水的渗透通量的影响因素62.3.静电纺丝技术的优势与局限性6第三章实验部分83.1.实验试剂83.2.实验仪器83.3.实验步骤83.3.1.PS溶液配制83.3.2.掺杂PDMS的PS溶液配制83.3.3.PS及其复合物纳米纤维无纺布的制备93.3.4.薄膜表面疏水性能的评价93.3.5.纤维形貌的表征9第四章结果与讨论104.1.纤维形貌的表征104.1.1 PDMS浓度对静电纺丝情况的影响104.1.2 掺杂PDMS的PS纳米纤维无纺布的形貌104.2.纤维表面润湿性能的表征12第五章实验结论15致谢16参考文献17附录19摘要近年来，随着仿生疏水表面的火热发展，科学家们对超疏水材料的研究也越来越热衷，近年来科学家们对此开展很长时间多方面的研究，这其中纳米纤维复合膜无纺布因为他的表面积大，多孔性，超疏水性等因素，在防腐去污等领域有着极其重要的发展潜力。本文章在利用静电纺丝的技术，制备了多孔不同浓度的PS与PDMS的纳米纤维无纺布，考察不同浓度的PDMS所形成的纳米纤维膜形貌特征，以及其润湿性的影响因素，并利用实验室接触角测定仪、光学显微镜等仪器，对PS与PDMS复合纳米纤维膜的物理性质来推测其疏水性与纤维表面接触角的影响，实验表明，PS与PDMS复合纳米纤维膜的纤维形貌与润湿行为都与PDMS的浓度有一定的关系。关键字：PS与PDMS复合纤维膜、疏水性、静电纺丝、纳米纤维、复合纤维润湿行为AbstractIn recent years, with the development of bionic fiery hydrophobic surface, scientists study of super-hydrophobic materials are increasingly keen, widely superhydrophobic materials applications, such as ship corrosion, rust metal, long-distance transmission and oil fields in the clothing waterproof stain clothing. In recent years, scientists have conducted extensive research on this for a long time, which nanofiber nonwoven composite film because of his large surface area, porosity, superhydrophobic and other factors, in areas such as antiseptic decontamination has an extremely important development potential, the paper around their wetting behavior of composite fiber morphology was studied.The absorbent article of nanofiber membrane using electrostatic spinning techniques, a porous PDMS with different concentrations of PS nano-fiber nonwoven fabric, the effects of different concentrations of PDMS is formed, and the effect of water separation characteristics, and use of contact angle